Bismuth(III) Complexes with Bis(dimethylphenyl) Dithiophosphates: Synthesis, Characterization and Crystal Structure of [{(3,5-CH3)2C6H3O}2PS2]3Bi

Bismuth(III) Complexes with Bis(dimethylphenyl) Dithiophosphates: Synthesis, Characterization and Crystal Structure of [{(3,5-CH3)2C6H3O}2PS2]3Bi

This work presents four complexes with general formula [{(ArO)2PS2}3Bi] (1–4), where Ar = 2,4-(CH3)2C6H3, 2,5-(CH3)2C6H3,3,4-(CH3)2C6H3 and3,5-(CH3)2C6H3, respectively. Reaction of [(ArO)2PS2Na] with Bi(NO3)3·5H2O in toluene in 3:1 molar stoichiometry afforded the complexes [{(ArO)2PS2}3Bi].These ne...

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Main Authors: Ruchi Khajuria, Sandeep Kumar, Mandeep Kour, Atiya Syed, Geeta Hundal, Sushil Kumar Pandey
Format: Article
Language:English
Published: Slovenian Chemical Society 2017-09-01
Series:Acta Chimica Slovenica
Subjects:
Bi(III) Complexes
X-ray
Dithiophosphate
Fungicidal
Online Access:https://journals.matheo.si/index.php/ACSi/article/view/3545
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spelling doaj-d0a75a5cf4424a8fb7887fa20cd9cc262020-11-25T01:55:04ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552017-09-0164367267810.17344/acsi.2017.3545501Bismuth(III) Complexes with Bis(dimethylphenyl) Dithiophosphates: Synthesis, Characterization and Crystal Structure of [{(3,5-CH3)2C6H3O}2PS2]3BiRuchi KhajuriaSandeep KumarMandeep KourAtiya SyedGeeta HundalSushil Kumar PandeyThis work presents four complexes with general formula [{(ArO)2PS2}3Bi] (1–4), where Ar = 2,4-(CH3)2C6H3, 2,5-(CH3)2C6H3,3,4-(CH3)2C6H3 and3,5-(CH3)2C6H3, respectively. Reaction of [(ArO)2PS2Na] with Bi(NO3)3·5H2O in toluene in 3:1 molar stoichiometry afforded the complexes [{(ArO)2PS2}3Bi].These newly synthesized complexes have been characterized by elemental analysis, FT-IR and multinuclear NMR (1H, 13C and 31P) NMR. The crystal structure of [{(3,5-CH3)2C6H3O}2PS2]3Bi (4) has been determined by X-ray crystallography. The compound crystallizes in monoclinic P21/c space group and Bi(III) centre is surrounded by six sulfur atoms from three symmetrically chelating bidentate diphenyl dithiophosphate ligands in a distorted octahedron environment. Screening these complexes for their antifungal activity against Pencillium chrysogenum gave positive results.https://journals.matheo.si/index.php/ACSi/article/view/3545Bi(III) ComplexesX-rayDithiophosphateFungicidal
collection DOAJ
language English
format Article
sources DOAJ
author Ruchi Khajuria
Sandeep Kumar
Mandeep Kour
Atiya Syed
Geeta Hundal
Sushil Kumar Pandey
spellingShingle Ruchi Khajuria
Sandeep Kumar
Mandeep Kour
Atiya Syed
Geeta Hundal
Sushil Kumar Pandey
Bismuth(III) Complexes with Bis(dimethylphenyl) Dithiophosphates: Synthesis, Characterization and Crystal Structure of [{(3,5-CH3)2C6H3O}2PS2]3Bi
Acta Chimica Slovenica
Bi(III) Complexes
X-ray
Dithiophosphate
Fungicidal
author_facet Ruchi Khajuria
Sandeep Kumar
Mandeep Kour
Atiya Syed
Geeta Hundal
Sushil Kumar Pandey
author_sort Ruchi Khajuria
title Bismuth(III) Complexes with Bis(dimethylphenyl) Dithiophosphates: Synthesis, Characterization and Crystal Structure of [{(3,5-CH3)2C6H3O}2PS2]3Bi
title_short Bismuth(III) Complexes with Bis(dimethylphenyl) Dithiophosphates: Synthesis, Characterization and Crystal Structure of [{(3,5-CH3)2C6H3O}2PS2]3Bi
title_full Bismuth(III) Complexes with Bis(dimethylphenyl) Dithiophosphates: Synthesis, Characterization and Crystal Structure of [{(3,5-CH3)2C6H3O}2PS2]3Bi
title_fullStr Bismuth(III) Complexes with Bis(dimethylphenyl) Dithiophosphates: Synthesis, Characterization and Crystal Structure of [{(3,5-CH3)2C6H3O}2PS2]3Bi
title_full_unstemmed Bismuth(III) Complexes with Bis(dimethylphenyl) Dithiophosphates: Synthesis, Characterization and Crystal Structure of [{(3,5-CH3)2C6H3O}2PS2]3Bi
title_sort bismuth(iii) complexes with bis(dimethylphenyl) dithiophosphates: synthesis, characterization and crystal structure of [{(3,5-ch3)2c6h3o}2ps2]3bi
publisher Slovenian Chemical Society
series Acta Chimica Slovenica
issn 1318-0207
1580-3155
publishDate 2017-09-01
description This work presents four complexes with general formula [{(ArO)2PS2}3Bi] (1–4), where Ar = 2,4-(CH3)2C6H3, 2,5-(CH3)2C6H3,3,4-(CH3)2C6H3 and3,5-(CH3)2C6H3, respectively. Reaction of [(ArO)2PS2Na] with Bi(NO3)3·5H2O in toluene in 3:1 molar stoichiometry afforded the complexes [{(ArO)2PS2}3Bi].These newly synthesized complexes have been characterized by elemental analysis, FT-IR and multinuclear NMR (1H, 13C and 31P) NMR. The crystal structure of [{(3,5-CH3)2C6H3O}2PS2]3Bi (4) has been determined by X-ray crystallography. The compound crystallizes in monoclinic P21/c space group and Bi(III) centre is surrounded by six sulfur atoms from three symmetrically chelating bidentate diphenyl dithiophosphate ligands in a distorted octahedron environment. Screening these complexes for their antifungal activity against Pencillium chrysogenum gave positive results.
topic Bi(III) Complexes
X-ray
Dithiophosphate
Fungicidal
url https://journals.matheo.si/index.php/ACSi/article/view/3545
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