Biomass-mediated synthesis of silver nanoparticles composite and application as green corrosion inhibitor in oilfield acidic cleaning fluid

Aqueous extract of red onion peels mediates the synthesis of silver nanoparticles composite (AqAgNPs). The AqAgNPs were characterized using X-ray diffraction, microscopic and spectroscopic techniques and evaluated as anticorrosion additive for pipeline (X80) steel. Spherical, stable, crystalline, mo...

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Main Authors:	Ekemini Ituen, Ambrish Singh, Lin Yuanhua, Onyewuchi Akaranta
Format:	Article
Language:	English
Published:	Elsevier 2021-07-01
Series:	Cleaner Engineering and Technology
Subjects:	Nanoscale characterization Nanocomposites Corrosion inhibitor AFM XRD TEM
Online Access:	http://www.sciencedirect.com/science/article/pii/S2666790821000793

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spelling	doaj-d01da3434fd545839849c99bd82d0b182021-06-17T04:49:01ZengElsevierCleaner Engineering and Technology2666-79082021-07-013100119Biomass-mediated synthesis of silver nanoparticles composite and application as green corrosion inhibitor in oilfield acidic cleaning fluidEkemini Ituen0Ambrish Singh1Lin Yuanhua2Onyewuchi Akaranta3State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, 610500, Sichuan, China; School of Materials Science and Engineering, Southwest Petroleum University, Chengdu, 610500, Sichuan, China; Emerging Materials and Energy Research Group, Department of Chemistry, University of Uyo, Uyo, Nigeria; Corresponding author. State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, 610500, Sichuan, China.State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, 610500, Sichuan, China; School of Materials Science and Engineering, Southwest Petroleum University, Chengdu, 610500, Sichuan, ChinaState Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, 610500, Sichuan, China; School of Materials Science and Engineering, Southwest Petroleum University, Chengdu, 610500, Sichuan, China; Corresponding author. State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, 610500, Sichuan, China.African Center of Excellence in Oilfield Chemicals Research, Institute of Petroleum Studies, University of Port Harcourt, NigeriaAqueous extract of red onion peels mediates the synthesis of silver nanoparticles composite (AqAgNPs). The AqAgNPs were characterized using X-ray diffraction, microscopic and spectroscopic techniques and evaluated as anticorrosion additive for pipeline (X80) steel. Spherical, stable, crystalline, monodisperse and non-agglomerated particles of 50 nm average size were obtained. In laboratory simulated acidic cleaning solution (1 M HCl), AqAgNPs exhibits impressive anticorrosion effect on X80 steel surface even at small concentrations (25% v/v) at 30–60 °C as determined by weight loss and electrochemical techniques. AqAgNPs is thermally and biochemically stable and still affords 86% efficiency at 60 °C even after 120 days of storage. FTIR and EDS studies reveal that AqAgNPs species interact with steel surface by adsorption using mainly by O and N sites. Microscopic (SEM and AFM) examination of the steel surface reveals sufficient protection and reduction in pitting by 70.5%. Instead of being discarded as waste, onion peels could be processed into oilfield chemicals as demonstrated in this study.http://www.sciencedirect.com/science/article/pii/S2666790821000793Nanoscale characterizationNanocompositesCorrosion inhibitorAFMXRDTEM
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Ekemini Ituen Ambrish Singh Lin Yuanhua Onyewuchi Akaranta
spellingShingle	Ekemini Ituen Ambrish Singh Lin Yuanhua Onyewuchi Akaranta Biomass-mediated synthesis of silver nanoparticles composite and application as green corrosion inhibitor in oilfield acidic cleaning fluid Cleaner Engineering and Technology Nanoscale characterization Nanocomposites Corrosion inhibitor AFM XRD TEM
author_facet	Ekemini Ituen Ambrish Singh Lin Yuanhua Onyewuchi Akaranta
author_sort	Ekemini Ituen
title	Biomass-mediated synthesis of silver nanoparticles composite and application as green corrosion inhibitor in oilfield acidic cleaning fluid
title_short	Biomass-mediated synthesis of silver nanoparticles composite and application as green corrosion inhibitor in oilfield acidic cleaning fluid
title_full	Biomass-mediated synthesis of silver nanoparticles composite and application as green corrosion inhibitor in oilfield acidic cleaning fluid
title_fullStr	Biomass-mediated synthesis of silver nanoparticles composite and application as green corrosion inhibitor in oilfield acidic cleaning fluid
title_full_unstemmed	Biomass-mediated synthesis of silver nanoparticles composite and application as green corrosion inhibitor in oilfield acidic cleaning fluid
title_sort	biomass-mediated synthesis of silver nanoparticles composite and application as green corrosion inhibitor in oilfield acidic cleaning fluid
publisher	Elsevier
series	Cleaner Engineering and Technology
issn	2666-7908
publishDate	2021-07-01
description	Aqueous extract of red onion peels mediates the synthesis of silver nanoparticles composite (AqAgNPs). The AqAgNPs were characterized using X-ray diffraction, microscopic and spectroscopic techniques and evaluated as anticorrosion additive for pipeline (X80) steel. Spherical, stable, crystalline, monodisperse and non-agglomerated particles of 50 nm average size were obtained. In laboratory simulated acidic cleaning solution (1 M HCl), AqAgNPs exhibits impressive anticorrosion effect on X80 steel surface even at small concentrations (25% v/v) at 30–60 °C as determined by weight loss and electrochemical techniques. AqAgNPs is thermally and biochemically stable and still affords 86% efficiency at 60 °C even after 120 days of storage. FTIR and EDS studies reveal that AqAgNPs species interact with steel surface by adsorption using mainly by O and N sites. Microscopic (SEM and AFM) examination of the steel surface reveals sufficient protection and reduction in pitting by 70.5%. Instead of being discarded as waste, onion peels could be processed into oilfield chemicals as demonstrated in this study.
topic	Nanoscale characterization Nanocomposites Corrosion inhibitor AFM XRD TEM
url	http://www.sciencedirect.com/science/article/pii/S2666790821000793
work_keys_str_mv	AT ekeminiituen biomassmediatedsynthesisofsilvernanoparticlescompositeandapplicationasgreencorrosioninhibitorinoilfieldacidiccleaningfluid AT ambrishsingh biomassmediatedsynthesisofsilvernanoparticlescompositeandapplicationasgreencorrosioninhibitorinoilfieldacidiccleaningfluid AT linyuanhua biomassmediatedsynthesisofsilvernanoparticlescompositeandapplicationasgreencorrosioninhibitorinoilfieldacidiccleaningfluid AT onyewuchiakaranta biomassmediatedsynthesisofsilvernanoparticlescompositeandapplicationasgreencorrosioninhibitorinoilfieldacidiccleaningfluid
_version_	1721374349878886400

Biomass-mediated synthesis of silver nanoparticles composite and application as green corrosion inhibitor in oilfield acidic cleaning fluid

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