High-Temperature Elastic Properties of Yttrium-Doped Barium Zirconate

• Main Authors: Fumitada Iguchi, Keisuke Hinata
• Format: Article
• Language: English
• Published: MDPI AG 2021-06-01
• Series: Metals
• Subjects: solid oxide fuel cell (SOFC); solid oxide electrolyzer cell (SOEC); proton conductor; perovskite; defect structure; hydration
• Online Access: https://www.mdpi.com/2075-4701/11/6/968

The elastic properties of 0, 10, 15, and 20 mol% yttrium-doped barium zirconate (BZY0, BZY10, BZY15, and BZY20) at the operating temperatures of protonic ceramic fuel cells were evaluated. The proposed measurement method for low sinterability materials could accurately determine the sonic velocities of small-pellet-type samples, and the elastic properties were determined based on these velocities. The Young’s modulus of BZY10, BZY15, and BZY20 was 224, 218, and 209 GPa at 20 °C, respectively, and the values decreased as the yttrium concentration increased. At high temperatures (>20 °C), as the temperature increased, the Young’s and shear moduli decreased, whereas the bulk modulus and Poisson’s ratio increased. The Young’s and shear moduli varied nonlinearly with the temperature: The values decreased rapidly from 100 to 300 °C and gradually at temperatures beyond 400 °C. The Young’s modulus of BZY10, BZY15, and BZY20 was 137, 159, and 122 GPa at 500 °C, respectively, 30–40% smaller than the values at 20 °C. The influence of the temperature was larger than that of the change in the yttrium concentration.