Femtosecond Mid-Infrared Study of the Aqueous Solution Photochemistry of a CO-Releasing Molecule (CORM)

Femtosecond Mid-Infrared Study of the Aqueous Solution Photochemistry of a CO-Releasing Molecule (CORM)

Ultraviolet irradiation of CO-releasing molecules (CORMs) in water eventually leads to the loss of several carbon monoxide ligands.We show for an exemplary manganese tricarbonyl CORM that only one ligand is photolyzed off on an ultrafast timescale and that some molecules may undergo geminate recombi...

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Main Authors: Schatzschneider U., Brixner T., Niesel J., Gehrig D., Kanal F., Rudolf P., Nuernberger P.
Format: Article
Language:English
Published: EDP Sciences 2013-03-01
Series:EPJ Web of Conferences
Online Access:http://dx.doi.org/10.1051/epjconf/20134105004
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spelling doaj-cee7f2d127ff47a19330454efa96b46f2021-08-02T04:24:35ZengEDP SciencesEPJ Web of Conferences2100-014X2013-03-01410500410.1051/epjconf/20134105004Femtosecond Mid-Infrared Study of the Aqueous Solution Photochemistry of a CO-Releasing Molecule (CORM)Schatzschneider U.Brixner T.Niesel J.Gehrig D.Kanal F.Rudolf P.Nuernberger P.Ultraviolet irradiation of CO-releasing molecules (CORMs) in water eventually leads to the loss of several carbon monoxide ligands.We show for an exemplary manganese tricarbonyl CORM that only one ligand is photolyzed off on an ultrafast timescale and that some molecules may undergo geminate recombination. http://dx.doi.org/10.1051/epjconf/20134105004
collection DOAJ
language English
format Article
sources DOAJ
author Schatzschneider U.
Brixner T.
Niesel J.
Gehrig D.
Kanal F.
Rudolf P.
Nuernberger P.
spellingShingle Schatzschneider U.
Brixner T.
Niesel J.
Gehrig D.
Kanal F.
Rudolf P.
Nuernberger P.
Femtosecond Mid-Infrared Study of the Aqueous Solution Photochemistry of a CO-Releasing Molecule (CORM)
EPJ Web of Conferences
author_facet Schatzschneider U.
Brixner T.
Niesel J.
Gehrig D.
Kanal F.
Rudolf P.
Nuernberger P.
author_sort Schatzschneider U.
title Femtosecond Mid-Infrared Study of the Aqueous Solution Photochemistry of a CO-Releasing Molecule (CORM)
title_short Femtosecond Mid-Infrared Study of the Aqueous Solution Photochemistry of a CO-Releasing Molecule (CORM)
title_full Femtosecond Mid-Infrared Study of the Aqueous Solution Photochemistry of a CO-Releasing Molecule (CORM)
title_fullStr Femtosecond Mid-Infrared Study of the Aqueous Solution Photochemistry of a CO-Releasing Molecule (CORM)
title_full_unstemmed Femtosecond Mid-Infrared Study of the Aqueous Solution Photochemistry of a CO-Releasing Molecule (CORM)
title_sort femtosecond mid-infrared study of the aqueous solution photochemistry of a co-releasing molecule (corm)
publisher EDP Sciences
series EPJ Web of Conferences
issn 2100-014X
publishDate 2013-03-01
description Ultraviolet irradiation of CO-releasing molecules (CORMs) in water eventually leads to the loss of several carbon monoxide ligands.We show for an exemplary manganese tricarbonyl CORM that only one ligand is photolyzed off on an ultrafast timescale and that some molecules may undergo geminate recombination.
url http://dx.doi.org/10.1051/epjconf/20134105004
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AT nieselj femtosecondmidinfraredstudyoftheaqueoussolutionphotochemistryofacoreleasingmoleculecorm
AT gehrigd femtosecondmidinfraredstudyoftheaqueoussolutionphotochemistryofacoreleasingmoleculecorm
AT kanalf femtosecondmidinfraredstudyoftheaqueoussolutionphotochemistryofacoreleasingmoleculecorm
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AT nuernbergerp femtosecondmidinfraredstudyoftheaqueoussolutionphotochemistryofacoreleasingmoleculecorm
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