Albendazole Degradation Possibilities by UV-Based Advanced Oxidation Processes

Pharmaceuticals are present in an aquatic environment usually in low (ng/L) concentrations. Their continuous release can lead to unwanted effects on the nontarget organisms. The main points of their collection and release into the environment are wastewater treatment plants. The wastewater treatment...

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Main Authors: Davor Ljubas, Mirta Čizmić, Katarina Vrbat, Draženka Stipaničev, Siniša Repec, Lidija Ćurković, Sandra Babić
Format: Article
Language:English
Published: Hindawi Limited 2018-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2018/6181747
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spelling doaj-cebbefaec1c94422afe42cdc871d215d2020-11-25T00:39:41ZengHindawi LimitedInternational Journal of Photoenergy1110-662X1687-529X2018-01-01201810.1155/2018/61817476181747Albendazole Degradation Possibilities by UV-Based Advanced Oxidation ProcessesDavor Ljubas0Mirta Čizmić1Katarina Vrbat2Draženka Stipaničev3Siniša Repec4Lidija Ćurković5Sandra Babić6Department of Energy, Power Engineering and Environment, Faculty of Mechanical Engineering and Naval Architecture, University of Zagreb, Ivana Lučića 5, Zagreb, CroatiaDepartment of Analytical Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 20, Zagreb, CroatiaDepartment of Analytical Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 20, Zagreb, CroatiaCroatian Waters, Central Water Management Laboratory, Ulica grada Vukovara 220, Zagreb, CroatiaCroatian Waters, Central Water Management Laboratory, Ulica grada Vukovara 220, Zagreb, CroatiaDepartment of Materials, Faculty of Mechanical Engineering and Naval Architecture, University of Zagreb, Ivana Lučića 5, Zagreb, CroatiaDepartment of Analytical Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 20, Zagreb, CroatiaPharmaceuticals are present in an aquatic environment usually in low (ng/L) concentrations. Their continuous release can lead to unwanted effects on the nontarget organisms. The main points of their collection and release into the environment are wastewater treatment plants. The wastewater treatment plants should be upgraded by new technologies, like advanced oxidation processes (AOPs), to be able to degrade these new pollutants. In this study, the degradation of albendazole (ALB), a drug against parasitic helminths, was investigated using four UV-based AOPs: UV photolysis, UV photocatalysis (over TiO2 film), UV + O3, and UV + H2O2. The ranking of the degradation process degree of the ALB and its degradation products for studied processes is as follows: UV photolysis < UV photocatalysis with TiO2 < UV + O3 < UV + H2O2. The fastest degradation of ALB and its degradation products was obtained by UV-C + H2O2 process with a degradation efficiency of 99.95%, achieved in 15 minutes.http://dx.doi.org/10.1155/2018/6181747
collection DOAJ
language English
format Article
sources DOAJ
author Davor Ljubas
Mirta Čizmić
Katarina Vrbat
Draženka Stipaničev
Siniša Repec
Lidija Ćurković
Sandra Babić
spellingShingle Davor Ljubas
Mirta Čizmić
Katarina Vrbat
Draženka Stipaničev
Siniša Repec
Lidija Ćurković
Sandra Babić
Albendazole Degradation Possibilities by UV-Based Advanced Oxidation Processes
International Journal of Photoenergy
author_facet Davor Ljubas
Mirta Čizmić
Katarina Vrbat
Draženka Stipaničev
Siniša Repec
Lidija Ćurković
Sandra Babić
author_sort Davor Ljubas
title Albendazole Degradation Possibilities by UV-Based Advanced Oxidation Processes
title_short Albendazole Degradation Possibilities by UV-Based Advanced Oxidation Processes
title_full Albendazole Degradation Possibilities by UV-Based Advanced Oxidation Processes
title_fullStr Albendazole Degradation Possibilities by UV-Based Advanced Oxidation Processes
title_full_unstemmed Albendazole Degradation Possibilities by UV-Based Advanced Oxidation Processes
title_sort albendazole degradation possibilities by uv-based advanced oxidation processes
publisher Hindawi Limited
series International Journal of Photoenergy
issn 1110-662X
1687-529X
publishDate 2018-01-01
description Pharmaceuticals are present in an aquatic environment usually in low (ng/L) concentrations. Their continuous release can lead to unwanted effects on the nontarget organisms. The main points of their collection and release into the environment are wastewater treatment plants. The wastewater treatment plants should be upgraded by new technologies, like advanced oxidation processes (AOPs), to be able to degrade these new pollutants. In this study, the degradation of albendazole (ALB), a drug against parasitic helminths, was investigated using four UV-based AOPs: UV photolysis, UV photocatalysis (over TiO2 film), UV + O3, and UV + H2O2. The ranking of the degradation process degree of the ALB and its degradation products for studied processes is as follows: UV photolysis < UV photocatalysis with TiO2 < UV + O3 < UV + H2O2. The fastest degradation of ALB and its degradation products was obtained by UV-C + H2O2 process with a degradation efficiency of 99.95%, achieved in 15 minutes.
url http://dx.doi.org/10.1155/2018/6181747
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