Deactivation of redox mediators in lithium-oxygen batteries by singlet oxygen
Redox mediators can enhance redox reactions in Li-O2 batteries; however, their gradual degradation remains unclear. Here the authors show that organic redox mediators are decomposed by singlet oxygen formed during cycling, indicating a strategy for the rational design of stable redox mediators.
Bibliographic Details
Main Authors: |
Won-Jin Kwak,
Hun Kim,
Yann K. Petit,
Christian Leypold,
Trung Thien Nguyen,
Nika Mahne,
Paul Redfern,
Larry A. Curtiss,
Hun-Gi Jung,
Sergey M. Borisov,
Stefan A. Freunberger,
Yang-Kook Sun |
Format: | Article
|
Language: | English |
Published: |
Nature Publishing Group
2019-03-01
|
Series: | Nature Communications
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Online Access: | https://doi.org/10.1038/s41467-019-09399-0
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