Research Update: The mechanocaloric potential of spin crossover compounds

We present a first evaluation of the potential for spin crossover (SCO) compounds to be considered as a new class of giant mechanocaloric effect materials. From literature data on the variation of the spin crossover temperature with pressure, we estimate the maximum available adiabatic temperature c...

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Bibliographic Details
Main Author: Karl G. Sandeman
Format: Article
Language:English
Published: AIP Publishing LLC 2016-11-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/1.4967282
Description
Summary:We present a first evaluation of the potential for spin crossover (SCO) compounds to be considered as a new class of giant mechanocaloric effect materials. From literature data on the variation of the spin crossover temperature with pressure, we estimate the maximum available adiabatic temperature change for several compounds and the relatively low pressures that may be required to observe these effects.
ISSN:2166-532X