Modification of Thionucleobases in Ionic Liquids

Modification of Thionucleobases in Ionic Liquids

A simple method was established for the preparation of thio-substituted thionucleobases using room temperature ionic liquids (RTILs) such as 1-butyl-3-methylimidazolium trifluoroacetate [BMIM]+[CF3COO]− and 1-methoxyethyl-3-methylimidazolium trifluoroacetate [MeOEtMIM]+[CF3COO]− as solvents and cata...

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Main Authors: Xiaomei Hu, Bixian Zhang, Shijia Dong, Yunfei Gao
Format: Article
Language:English
Published: Hindawi Limited 2014-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2014/353797
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spelling doaj-ce3564b177bb487682d26e41d49a723f2020-11-24T23:01:56ZengHindawi LimitedJournal of Chemistry2090-90632090-90712014-01-01201410.1155/2014/353797353797Modification of Thionucleobases in Ionic LiquidsXiaomei Hu0Bixian Zhang1Shijia Dong2Yunfei Gao3School of Life and Science, Northeast Agricultural University, Harbin 150030, ChinaHeilongjiang Academy of Agricultural Sciences, Harbin 150086, ChinaSchool of Life and Science, Northeast Agricultural University, Harbin 150030, ChinaHeilongjiang Academy of Agricultural Sciences, Harbin 150086, ChinaA simple method was established for the preparation of thio-substituted thionucleobases using room temperature ionic liquids (RTILs) such as 1-butyl-3-methylimidazolium trifluoroacetate [BMIM]+[CF3COO]− and 1-methoxyethyl-3-methylimidazolium trifluoroacetate [MeOEtMIM]+[CF3COO]− as solvents and catalysts without any other catalyst. These reactions proceeded efficiently in RTILs with excellent yield of products. RTILs can be recycled and reused effectively without further purification.http://dx.doi.org/10.1155/2014/353797
collection DOAJ
language English
format Article
sources DOAJ
author Xiaomei Hu
Bixian Zhang
Shijia Dong
Yunfei Gao
spellingShingle Xiaomei Hu
Bixian Zhang
Shijia Dong
Yunfei Gao
Modification of Thionucleobases in Ionic Liquids
Journal of Chemistry
author_facet Xiaomei Hu
Bixian Zhang
Shijia Dong
Yunfei Gao
author_sort Xiaomei Hu
title Modification of Thionucleobases in Ionic Liquids
title_short Modification of Thionucleobases in Ionic Liquids
title_full Modification of Thionucleobases in Ionic Liquids
title_fullStr Modification of Thionucleobases in Ionic Liquids
title_full_unstemmed Modification of Thionucleobases in Ionic Liquids
title_sort modification of thionucleobases in ionic liquids
publisher Hindawi Limited
series Journal of Chemistry
issn 2090-9063
2090-9071
publishDate 2014-01-01
description A simple method was established for the preparation of thio-substituted thionucleobases using room temperature ionic liquids (RTILs) such as 1-butyl-3-methylimidazolium trifluoroacetate [BMIM]+[CF3COO]− and 1-methoxyethyl-3-methylimidazolium trifluoroacetate [MeOEtMIM]+[CF3COO]− as solvents and catalysts without any other catalyst. These reactions proceeded efficiently in RTILs with excellent yield of products. RTILs can be recycled and reused effectively without further purification.
url http://dx.doi.org/10.1155/2014/353797
work_keys_str_mv AT xiaomeihu modificationofthionucleobasesinionicliquids
AT bixianzhang modificationofthionucleobasesinionicliquids
AT shijiadong modificationofthionucleobasesinionicliquids
AT yunfeigao modificationofthionucleobasesinionicliquids
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