Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water

The TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> composites were prepared by the hydrothermal method with cetyltrimethyl ammonium bromide (CTAB). The influence of CTAB on the structural properties and spectral properties of the composites was studied. The samples...

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Main Authors: ZENG Bao-ping, JIA Ying, XU Guo-gen, LI Ming, FENG Rui
Format: Article
Language:zho
Published: Journal of Materials Engineering 2019-09-01
Series:Journal of Materials Engineering
Subjects:
Online Access:http://jme.biam.ac.cn/CN/Y2019/V47/I9/139
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spelling doaj-cdd8bd0d3f3e4c50a479552f38acca562020-11-25T01:31:36ZzhoJournal of Materials EngineeringJournal of Materials Engineering1001-43811001-43812019-09-0147913914410.11868/j.issn.1001-4381.2017.000933201909000933Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste waterZENG Bao-ping0JIA Ying1XU Guo-gen2LI Ming3FENG Rui4Rocket Force University of Engineering, Xi'an 710025, ChinaRocket Force University of Engineering, Xi'an 710025, ChinaRocket Force University of Engineering, Xi'an 710025, ChinaRocket Force University of Engineering, Xi'an 710025, ChinaRocket Force University of Engineering, Xi'an 710025, ChinaThe TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> composites were prepared by the hydrothermal method with cetyltrimethyl ammonium bromide (CTAB). The influence of CTAB on the structural properties and spectral properties of the composites was studied. The samples were characterized by XRD, TEM, N<sub>2</sub> adsorption-desorption, FT-IR, UV-Vis DRS and PL, meanwhile, the samples were used to degrade unsymmetrical dimethyl hydrazine (UDMH) wastewater under visible light. The results show that the crystal structure of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> composites assisted by CTAB is intact,with smaller particle size of nanoparticles and uniformly distributed on g-C<sub>3</sub>N<sub>4</sub> sheets. The specific surface area of the composites increases and the mesoporous is more abundant, the adsorption ledge of the composites is expanded to 450nm, the recombination rate of hole-electron reduces obviously. Photocatalytic results show that the UDMH degradation efficiency of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> (CTAB) reaches 83.2% in 120min, which is improved by 13.7% than that of the no CTAB-assisted composites.http://jme.biam.ac.cn/CN/Y2019/V47/I9/139ctabtio<sub>2</sub>/g-c<sub>3</sub>n<sub>4</sub>photocatalysisunsymmetrical dimethylhydrazine
collection DOAJ
language zho
format Article
sources DOAJ
author ZENG Bao-ping
JIA Ying
XU Guo-gen
LI Ming
FENG Rui
spellingShingle ZENG Bao-ping
JIA Ying
XU Guo-gen
LI Ming
FENG Rui
Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water
Journal of Materials Engineering
ctab
tio<sub>2</sub>/g-c<sub>3</sub>n<sub>4</sub>
photocatalysis
unsymmetrical dimethylhydrazine
author_facet ZENG Bao-ping
JIA Ying
XU Guo-gen
LI Ming
FENG Rui
author_sort ZENG Bao-ping
title Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water
title_short Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water
title_full Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water
title_fullStr Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water
title_full_unstemmed Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water
title_sort preparation of tio<sub>2</sub>/g-c<sub>3</sub>n<sub>4</sub> by ctab-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water
publisher Journal of Materials Engineering
series Journal of Materials Engineering
issn 1001-4381
1001-4381
publishDate 2019-09-01
description The TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> composites were prepared by the hydrothermal method with cetyltrimethyl ammonium bromide (CTAB). The influence of CTAB on the structural properties and spectral properties of the composites was studied. The samples were characterized by XRD, TEM, N<sub>2</sub> adsorption-desorption, FT-IR, UV-Vis DRS and PL, meanwhile, the samples were used to degrade unsymmetrical dimethyl hydrazine (UDMH) wastewater under visible light. The results show that the crystal structure of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> composites assisted by CTAB is intact,with smaller particle size of nanoparticles and uniformly distributed on g-C<sub>3</sub>N<sub>4</sub> sheets. The specific surface area of the composites increases and the mesoporous is more abundant, the adsorption ledge of the composites is expanded to 450nm, the recombination rate of hole-electron reduces obviously. Photocatalytic results show that the UDMH degradation efficiency of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> (CTAB) reaches 83.2% in 120min, which is improved by 13.7% than that of the no CTAB-assisted composites.
topic ctab
tio<sub>2</sub>/g-c<sub>3</sub>n<sub>4</sub>
photocatalysis
unsymmetrical dimethylhydrazine
url http://jme.biam.ac.cn/CN/Y2019/V47/I9/139
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