Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water
The TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> composites were prepared by the hydrothermal method with cetyltrimethyl ammonium bromide (CTAB). The influence of CTAB on the structural properties and spectral properties of the composites was studied. The samples...
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doaj-cdd8bd0d3f3e4c50a479552f38acca562020-11-25T01:31:36ZzhoJournal of Materials EngineeringJournal of Materials Engineering1001-43811001-43812019-09-0147913914410.11868/j.issn.1001-4381.2017.000933201909000933Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste waterZENG Bao-ping0JIA Ying1XU Guo-gen2LI Ming3FENG Rui4Rocket Force University of Engineering, Xi'an 710025, ChinaRocket Force University of Engineering, Xi'an 710025, ChinaRocket Force University of Engineering, Xi'an 710025, ChinaRocket Force University of Engineering, Xi'an 710025, ChinaRocket Force University of Engineering, Xi'an 710025, ChinaThe TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> composites were prepared by the hydrothermal method with cetyltrimethyl ammonium bromide (CTAB). The influence of CTAB on the structural properties and spectral properties of the composites was studied. The samples were characterized by XRD, TEM, N<sub>2</sub> adsorption-desorption, FT-IR, UV-Vis DRS and PL, meanwhile, the samples were used to degrade unsymmetrical dimethyl hydrazine (UDMH) wastewater under visible light. The results show that the crystal structure of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> composites assisted by CTAB is intact,with smaller particle size of nanoparticles and uniformly distributed on g-C<sub>3</sub>N<sub>4</sub> sheets. The specific surface area of the composites increases and the mesoporous is more abundant, the adsorption ledge of the composites is expanded to 450nm, the recombination rate of hole-electron reduces obviously. Photocatalytic results show that the UDMH degradation efficiency of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> (CTAB) reaches 83.2% in 120min, which is improved by 13.7% than that of the no CTAB-assisted composites.http://jme.biam.ac.cn/CN/Y2019/V47/I9/139ctabtio<sub>2</sub>/g-c<sub>3</sub>n<sub>4</sub>photocatalysisunsymmetrical dimethylhydrazine |
collection |
DOAJ |
language |
zho |
format |
Article |
sources |
DOAJ |
author |
ZENG Bao-ping JIA Ying XU Guo-gen LI Ming FENG Rui |
spellingShingle |
ZENG Bao-ping JIA Ying XU Guo-gen LI Ming FENG Rui Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water Journal of Materials Engineering ctab tio<sub>2</sub>/g-c<sub>3</sub>n<sub>4</sub> photocatalysis unsymmetrical dimethylhydrazine |
author_facet |
ZENG Bao-ping JIA Ying XU Guo-gen LI Ming FENG Rui |
author_sort |
ZENG Bao-ping |
title |
Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water |
title_short |
Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water |
title_full |
Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water |
title_fullStr |
Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water |
title_full_unstemmed |
Preparation of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> by CTAB-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water |
title_sort |
preparation of tio<sub>2</sub>/g-c<sub>3</sub>n<sub>4</sub> by ctab-assisted and photocatalytic degradation of unsymmetrical dimethylhydrazine waste water |
publisher |
Journal of Materials Engineering |
series |
Journal of Materials Engineering |
issn |
1001-4381 1001-4381 |
publishDate |
2019-09-01 |
description |
The TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> composites were prepared by the hydrothermal method with cetyltrimethyl ammonium bromide (CTAB). The influence of CTAB on the structural properties and spectral properties of the composites was studied. The samples were characterized by XRD, TEM, N<sub>2</sub> adsorption-desorption, FT-IR, UV-Vis DRS and PL, meanwhile, the samples were used to degrade unsymmetrical dimethyl hydrazine (UDMH) wastewater under visible light. The results show that the crystal structure of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> composites assisted by CTAB is intact,with smaller particle size of nanoparticles and uniformly distributed on g-C<sub>3</sub>N<sub>4</sub> sheets. The specific surface area of the composites increases and the mesoporous is more abundant, the adsorption ledge of the composites is expanded to 450nm, the recombination rate of hole-electron reduces obviously. Photocatalytic results show that the UDMH degradation efficiency of TiO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> (CTAB) reaches 83.2% in 120min, which is improved by 13.7% than that of the no CTAB-assisted composites. |
topic |
ctab tio<sub>2</sub>/g-c<sub>3</sub>n<sub>4</sub> photocatalysis unsymmetrical dimethylhydrazine |
url |
http://jme.biam.ac.cn/CN/Y2019/V47/I9/139 |
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