trans-K3[TcO2(CN)4]
The structure of the title compound, tripotassium trans-tetracyanidodioxidotechnetate(V), is isotypic with its Re analogue. The [TcO2(CN)4]3− trans-tetracyanidodioxidotechnetate anion has a slightly distorted octahedral configuration. The Tc atom is located on a center of inversion and...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810028205 |
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doaj-cdc708be0c484f3dbd578be1ec7aea842020-11-24T21:21:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668i61i6210.1107/S1600536810028205trans-K3[TcO2(CN)4]Sayandev ChatterjeeAndrew S. Del NegroMatthew K. EdwardsBrendan TwamleyJeanette A. KrauseSamuel A. BryanThe structure of the title compound, tripotassium trans-tetracyanidodioxidotechnetate(V), is isotypic with its Re analogue. The [TcO2(CN)4]3− trans-tetracyanidodioxidotechnetate anion has a slightly distorted octahedral configuration. The Tc atom is located on a center of inversion and is bound to two O atoms in axial and to four cyanide ligands in equatorial positions. The Tc—O distance is consistent with a double-bond character. The two potassium cations, one located on a center of inversion and one in a general position, reside in octahedral or tetrahedral environments, respectively. K...O and K...N interactions occur in the 2.7877 (19)–2.8598 (15) Å range. http://scripts.iucr.org/cgi-bin/paper?S1600536810028205 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Sayandev Chatterjee Andrew S. Del Negro Matthew K. Edwards Brendan Twamley Jeanette A. Krause Samuel A. Bryan |
| spellingShingle |
Sayandev Chatterjee Andrew S. Del Negro Matthew K. Edwards Brendan Twamley Jeanette A. Krause Samuel A. Bryan trans-K3[TcO2(CN)4] Acta Crystallographica Section E |
| author_facet |
Sayandev Chatterjee Andrew S. Del Negro Matthew K. Edwards Brendan Twamley Jeanette A. Krause Samuel A. Bryan |
| author_sort |
Sayandev Chatterjee |
| title |
trans-K3[TcO2(CN)4] |
| title_short |
trans-K3[TcO2(CN)4] |
| title_full |
trans-K3[TcO2(CN)4] |
| title_fullStr |
trans-K3[TcO2(CN)4] |
| title_full_unstemmed |
trans-K3[TcO2(CN)4] |
| title_sort |
trans-k3[tco2(cn)4] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2010-08-01 |
| description |
The structure of the title compound, tripotassium trans-tetracyanidodioxidotechnetate(V), is isotypic with its Re analogue. The [TcO2(CN)4]3− trans-tetracyanidodioxidotechnetate anion has a slightly distorted octahedral configuration. The Tc atom is located on a center of inversion and is bound to two O atoms in axial and to four cyanide ligands in equatorial positions. The Tc—O distance is consistent with a double-bond character. The two potassium cations, one located on a center of inversion and one in a general position, reside in octahedral or tetrahedral environments, respectively. K...O and K...N interactions occur in the 2.7877 (19)–2.8598 (15) Å range. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810028205 |
| work_keys_str_mv |
AT sayandevchatterjee transk3tco2cn4 AT andrewsdelnegro transk3tco2cn4 AT matthewkedwards transk3tco2cn4 AT brendantwamley transk3tco2cn4 AT jeanetteakrause transk3tco2cn4 AT samuelabryan transk3tco2cn4 |
| _version_ |
1726000960584548352 |