Poly[[pentaaquabis(μ3-hydrogen squarato)barium] monohydrate]

Poly[[pentaaquabis(μ3-hydrogen squarato)barium] monohydrate]

The crystal structure of the title compound, {[Ba(C4HO4)2(H2O)5]·H2O}n, consists of discrete double chains propagating along [010]. The chains are formed by BaII ions linked by bridging hydrogen squarate ligands in a trans-bis-monodentate mode. In addition, the bridging hydrogen squarate li...

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Main Authors: Chahrazed Trifa, Amira Bouhali, Sofiane Bouacida, Chaouki Boudaren, Hocine Merazig
Format: Article
Language:English
Published: International Union of Crystallography 2013-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813014736
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spelling doaj-cd98ded839eb4e67b0e14ec2caf530d82020-11-25T00:17:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-07-01697m366m36710.1107/S1600536813014736Poly[[pentaaquabis(μ3-hydrogen squarato)barium] monohydrate]Chahrazed TrifaAmira BouhaliSofiane BouacidaChaouki BoudarenHocine MerazigThe crystal structure of the title compound, {[Ba(C4HO4)2(H2O)5]·H2O}n, consists of discrete double chains propagating along [010]. The chains are formed by BaII ions linked by bridging hydrogen squarate ligands in a trans-bis-monodentate mode. In addition, the bridging hydrogen squarate ligands connect the chains into a ladder structure via a third coordinating O atom. The remaining coordination sites are occupied by five aqua ligands and a second mondendate hydrogen squarate ligand, forming a slightly distorted tricapped trigonal–prismatic geometry. O—H...O hydrogen bonds link the chains and solvent water molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536813014736
collection DOAJ
language English
format Article
sources DOAJ
author Chahrazed Trifa
Amira Bouhali
Sofiane Bouacida
Chaouki Boudaren
Hocine Merazig
spellingShingle Chahrazed Trifa
Amira Bouhali
Sofiane Bouacida
Chaouki Boudaren
Hocine Merazig
Poly[[pentaaquabis(μ3-hydrogen squarato)barium] monohydrate]
Acta Crystallographica Section E
author_facet Chahrazed Trifa
Amira Bouhali
Sofiane Bouacida
Chaouki Boudaren
Hocine Merazig
author_sort Chahrazed Trifa
title Poly[[pentaaquabis(μ3-hydrogen squarato)barium] monohydrate]
title_short Poly[[pentaaquabis(μ3-hydrogen squarato)barium] monohydrate]
title_full Poly[[pentaaquabis(μ3-hydrogen squarato)barium] monohydrate]
title_fullStr Poly[[pentaaquabis(μ3-hydrogen squarato)barium] monohydrate]
title_full_unstemmed Poly[[pentaaquabis(μ3-hydrogen squarato)barium] monohydrate]
title_sort poly[[pentaaquabis(μ3-hydrogen squarato)barium] monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-07-01
description The crystal structure of the title compound, {[Ba(C4HO4)2(H2O)5]·H2O}n, consists of discrete double chains propagating along [010]. The chains are formed by BaII ions linked by bridging hydrogen squarate ligands in a trans-bis-monodentate mode. In addition, the bridging hydrogen squarate ligands connect the chains into a ladder structure via a third coordinating O atom. The remaining coordination sites are occupied by five aqua ligands and a second mondendate hydrogen squarate ligand, forming a slightly distorted tricapped trigonal–prismatic geometry. O—H...O hydrogen bonds link the chains and solvent water molecules into a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813014736
work_keys_str_mv AT chahrazedtrifa polypentaaquabis9563hydrogensquaratobariummonohydrate
AT amirabouhali polypentaaquabis9563hydrogensquaratobariummonohydrate
AT sofianebouacida polypentaaquabis9563hydrogensquaratobariummonohydrate
AT chaoukiboudaren polypentaaquabis9563hydrogensquaratobariummonohydrate
AT hocinemerazig polypentaaquabis9563hydrogensquaratobariummonohydrate
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