The Effect of Active Material, Conductive Additives, and Binder in a Cathode Composite Electrode on Battery Performance

The current study investigated the effects of active material, conductive additives, and binder in a composite electrode on battery performance. In addition, the parameters related to cell performance as well as side reactions were integrated in an electrochemical model. In order to predict the cell...

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Bibliographic Details
Main Author: Yoon Koo Lee
Format: Article
Language:English
Published: MDPI AG 2019-02-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/12/4/658
Description
Summary:The current study investigated the effects of active material, conductive additives, and binder in a composite electrode on battery performance. In addition, the parameters related to cell performance as well as side reactions were integrated in an electrochemical model. In order to predict the cell performance, key parameters including manganese dissolution, electronic conductivity, and resistance were first measured through experiments. Experimental results determined that a higher ratio of polymer binder to conductive additives increased the interfacial resistance, and a higher ratio of conductive additives to polymer binder in the electrode resulted in an increase in dissolved transition metal ions from the LiMn<sub>2</sub>O<sub>4</sub> composite electrode. By performing a degradation simulation with these parameters, battery capacity was predicted with various fractions of constituents in the composite electrode. The present study shows that by using this integrated prediction method, the optimal ratio of constituents for a particular cathode composite electrode can be specified that will maximize battery performance.
ISSN:1996-1073