A fluorescent paramagnetic Mn metal–organic framework based on semi-rigid pyrene tetracarboxylic acid: sensing of solvent polarity and explosive nitroaromatics

A fluorescent paramagnetic Mn metal–organic framework based on semi-rigid pyrene tetracarboxylic acid: sensing of solvent polarity and explosive nitroaromatics

An Mn metal–organic framework (Mn-MOF), Mn-L, based on a pyrene-tetraacid linker (H4L), displays a respectable fluorescence quantum yield of 8.3% in spite of the presence of the paramagnetic metal ions, due presumably to fixation of the metal ions in geometries that do not allow complete energy/char...

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Bibliographic Details
Main Authors: Alankriti Bajpai, Arindam Mukhopadhyay, Manchugondanahalli Shivakumar Krishna, Savitha Govardhan, Jarugu Narasimha Moorthy
Format: Article
Language:English
Published: International Union of Crystallography 2015-09-01
Series:IUCrJ
Subjects:
crystal structure
metal–organic framework
solvatochromism
fluorescence
sensing
nitroaromatics
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2052252515012506

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http://scripts.iucr.org/cgi-bin/paper?S2052252515012506

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