Synthesis and characterization of novel polyester containing Schiff-base unit

Abstract A new Schiff base type of polyester containing 2,2-dimethyl-1,3-diaminopropane was prepared by solution polycondensation of 1,4-benzenedicarbonyl dichloride with Bis(4-hydroxybenzilaldehid)-2,2-dimethyl-1,3-propildiimine (H2HB2P) which is derived from a 2,2-dimethyl-1,3-diaminopropane Schif...

Full description

Bibliographic Details
Main Authors: Hossein Mighani, Ehsan Fathollahi, Moosa Ghaemy
Format: Article
Language:English
Published: Associação Brasileira de Polímeros 2015-10-01
Series:Polímeros
Subjects:
2
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282015000500005&lng=en&tlng=en
id doaj-ccb5ac8e58dc4ac79fefdb2d139a3b00
record_format Article
spelling doaj-ccb5ac8e58dc4ac79fefdb2d139a3b002020-11-25T00:32:52ZengAssociação Brasileira de PolímerosPolímeros1678-51692015-10-0125544745010.1590/0104-1428.1911S0104-14282015000500005Synthesis and characterization of novel polyester containing Schiff-base unitHossein MighaniEhsan FathollahiMoosa GhaemyAbstract A new Schiff base type of polyester containing 2,2-dimethyl-1,3-diaminopropane was prepared by solution polycondensation of 1,4-benzenedicarbonyl dichloride with Bis(4-hydroxybenzilaldehid)-2,2-dimethyl-1,3-propildiimine (H2HB2P) which is derived from a 2,2-dimethyl-1,3-diaminopropane Schiff base reacted with a 4-hydroxybenzaldehyde monomer. The monomer and the polyester were characterized by FTIR,1HNMR, and elemental analysis. The prepared polyester showed inherent viscosity of 0.29 dl/g in NMP at 25 °C, indicating their moderate molecular weight. The Polyester was completely soluble in aprotic polar solvents such asN -methylpyrolidone (NMP), dimethylformamide (DMF), Dimethyl Acetamid (DMAC), dimthylsulfoxide (DMSO). TGA determined the 10% weight loss temperature (T10) at 280 °C and residual weight at 600 °C ca. 41% under nitrogen atmosphere.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282015000500005&lng=en&tlng=enpolyesterSchiff base22-dimethyl-13-diaminopropanethermal stability
collection DOAJ
language English
format Article
sources DOAJ
author Hossein Mighani
Ehsan Fathollahi
Moosa Ghaemy
spellingShingle Hossein Mighani
Ehsan Fathollahi
Moosa Ghaemy
Synthesis and characterization of novel polyester containing Schiff-base unit
Polímeros
polyester
Schiff base
2
2-dimethyl-1
3-diaminopropane
thermal stability
author_facet Hossein Mighani
Ehsan Fathollahi
Moosa Ghaemy
author_sort Hossein Mighani
title Synthesis and characterization of novel polyester containing Schiff-base unit
title_short Synthesis and characterization of novel polyester containing Schiff-base unit
title_full Synthesis and characterization of novel polyester containing Schiff-base unit
title_fullStr Synthesis and characterization of novel polyester containing Schiff-base unit
title_full_unstemmed Synthesis and characterization of novel polyester containing Schiff-base unit
title_sort synthesis and characterization of novel polyester containing schiff-base unit
publisher Associação Brasileira de Polímeros
series Polímeros
issn 1678-5169
publishDate 2015-10-01
description Abstract A new Schiff base type of polyester containing 2,2-dimethyl-1,3-diaminopropane was prepared by solution polycondensation of 1,4-benzenedicarbonyl dichloride with Bis(4-hydroxybenzilaldehid)-2,2-dimethyl-1,3-propildiimine (H2HB2P) which is derived from a 2,2-dimethyl-1,3-diaminopropane Schiff base reacted with a 4-hydroxybenzaldehyde monomer. The monomer and the polyester were characterized by FTIR,1HNMR, and elemental analysis. The prepared polyester showed inherent viscosity of 0.29 dl/g in NMP at 25 °C, indicating their moderate molecular weight. The Polyester was completely soluble in aprotic polar solvents such asN -methylpyrolidone (NMP), dimethylformamide (DMF), Dimethyl Acetamid (DMAC), dimthylsulfoxide (DMSO). TGA determined the 10% weight loss temperature (T10) at 280 °C and residual weight at 600 °C ca. 41% under nitrogen atmosphere.
topic polyester
Schiff base
2
2-dimethyl-1
3-diaminopropane
thermal stability
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282015000500005&lng=en&tlng=en
work_keys_str_mv AT hosseinmighani synthesisandcharacterizationofnovelpolyestercontainingschiffbaseunit
AT ehsanfathollahi synthesisandcharacterizationofnovelpolyestercontainingschiffbaseunit
AT moosaghaemy synthesisandcharacterizationofnovelpolyestercontainingschiffbaseunit
_version_ 1725318622663933952