Synthesis and characterization of novel polyester containing Schiff-base unit
Abstract A new Schiff base type of polyester containing 2,2-dimethyl-1,3-diaminopropane was prepared by solution polycondensation of 1,4-benzenedicarbonyl dichloride with Bis(4-hydroxybenzilaldehid)-2,2-dimethyl-1,3-propildiimine (H2HB2P) which is derived from a 2,2-dimethyl-1,3-diaminopropane Schif...
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Associação Brasileira de Polímeros
2015-10-01
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doaj-ccb5ac8e58dc4ac79fefdb2d139a3b002020-11-25T00:32:52ZengAssociação Brasileira de PolímerosPolímeros1678-51692015-10-0125544745010.1590/0104-1428.1911S0104-14282015000500005Synthesis and characterization of novel polyester containing Schiff-base unitHossein MighaniEhsan FathollahiMoosa GhaemyAbstract A new Schiff base type of polyester containing 2,2-dimethyl-1,3-diaminopropane was prepared by solution polycondensation of 1,4-benzenedicarbonyl dichloride with Bis(4-hydroxybenzilaldehid)-2,2-dimethyl-1,3-propildiimine (H2HB2P) which is derived from a 2,2-dimethyl-1,3-diaminopropane Schiff base reacted with a 4-hydroxybenzaldehyde monomer. The monomer and the polyester were characterized by FTIR,1HNMR, and elemental analysis. The prepared polyester showed inherent viscosity of 0.29 dl/g in NMP at 25 °C, indicating their moderate molecular weight. The Polyester was completely soluble in aprotic polar solvents such asN -methylpyrolidone (NMP), dimethylformamide (DMF), Dimethyl Acetamid (DMAC), dimthylsulfoxide (DMSO). TGA determined the 10% weight loss temperature (T10) at 280 °C and residual weight at 600 °C ca. 41% under nitrogen atmosphere.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282015000500005&lng=en&tlng=enpolyesterSchiff base22-dimethyl-13-diaminopropanethermal stability |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Hossein Mighani Ehsan Fathollahi Moosa Ghaemy |
spellingShingle |
Hossein Mighani Ehsan Fathollahi Moosa Ghaemy Synthesis and characterization of novel polyester containing Schiff-base unit Polímeros polyester Schiff base 2 2-dimethyl-1 3-diaminopropane thermal stability |
author_facet |
Hossein Mighani Ehsan Fathollahi Moosa Ghaemy |
author_sort |
Hossein Mighani |
title |
Synthesis and characterization of novel polyester containing Schiff-base unit |
title_short |
Synthesis and characterization of novel polyester containing Schiff-base unit |
title_full |
Synthesis and characterization of novel polyester containing Schiff-base unit |
title_fullStr |
Synthesis and characterization of novel polyester containing Schiff-base unit |
title_full_unstemmed |
Synthesis and characterization of novel polyester containing Schiff-base unit |
title_sort |
synthesis and characterization of novel polyester containing schiff-base unit |
publisher |
Associação Brasileira de Polímeros |
series |
Polímeros |
issn |
1678-5169 |
publishDate |
2015-10-01 |
description |
Abstract A new Schiff base type of polyester containing 2,2-dimethyl-1,3-diaminopropane was prepared by solution polycondensation of 1,4-benzenedicarbonyl dichloride with Bis(4-hydroxybenzilaldehid)-2,2-dimethyl-1,3-propildiimine (H2HB2P) which is derived from a 2,2-dimethyl-1,3-diaminopropane Schiff base reacted with a 4-hydroxybenzaldehyde monomer. The monomer and the polyester were characterized by FTIR,1HNMR, and elemental analysis. The prepared polyester showed inherent viscosity of 0.29 dl/g in NMP at 25 °C, indicating their moderate molecular weight. The Polyester was completely soluble in aprotic polar solvents such asN -methylpyrolidone (NMP), dimethylformamide (DMF), Dimethyl Acetamid (DMAC), dimthylsulfoxide (DMSO). TGA determined the 10% weight loss temperature (T10) at 280 °C and residual weight at 600 °C ca. 41% under nitrogen atmosphere. |
topic |
polyester Schiff base 2 2-dimethyl-1 3-diaminopropane thermal stability |
url |
http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282015000500005&lng=en&tlng=en |
work_keys_str_mv |
AT hosseinmighani synthesisandcharacterizationofnovelpolyestercontainingschiffbaseunit AT ehsanfathollahi synthesisandcharacterizationofnovelpolyestercontainingschiffbaseunit AT moosaghaemy synthesisandcharacterizationofnovelpolyestercontainingschiffbaseunit |
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