Di-μ-thiocyanato-bis[bis(tri-p-tolylphosphine)silver(I)] 0.35-hydrate

Di-μ-thiocyanato-bis[bis(tri-p-tolylphosphine)silver(I)] 0.35-hydrate

In the binuclear centrosymmetric title compound, [Ag2(NCS)2(C21H21P)4]·0.35H2O, a pseudo-polymorph of [Ag2(NCS)2(C21H21P)4]·2CH3CN, the Ag atom is coordinated by two phosphine ligands and two bridging thiocyanate ligands in a distorted tetrahedral configuration. The crystal...

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Bibliographic Details
Main Authors: Nozipho M. Khumalo, Reinout Meijboom, Alfred Muller, Bernard Omondi
Format: Article
Language:English
Published: International Union of Crystallography 2010-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810010032
Description
Summary:In the binuclear centrosymmetric title compound, [Ag2(NCS)2(C21H21P)4]·0.35H2O, a pseudo-polymorph of [Ag2(NCS)2(C21H21P)4]·2CH3CN, the Ag atom is coordinated by two phosphine ligands and two bridging thiocyanate ligands in a distorted tetrahedral configuration. The crystal structure exhibits intermolecular C—H...π interactions.
ISSN:1600-5368

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