Bis(μ-2-hydroxymethyl-2-methylpropane-1,3-diolato)bis[dichloridotitanium(IV)] diethyl ether disolvate

Bis(μ-2-hydroxymethyl-2-methylpropane-1,3-diolato)bis[dichloridotitanium(IV)] diethyl ether disolvate

The title complex, [Ti2Cl4{CH3C(CH2O)2(CH2OH)}2], lies across a centre of symmetry with a diethyl ether solvent molecule hydrogen bonded to the –CH2OH groups on either side of it. The TiIV atom is coordinated in a distorted octahedral geometry by a tripodal ligand and two terminal chloride...

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Main Authors: Joyce M. Waters, Chaohong Shen, Alastair J. Nielson
Format: Article
Language:English
Published: International Union of Crystallography 2013-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813031504
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spelling doaj-cc6cefc3fdc548f7812159a2f7eb20b12020-11-24T22:14:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-12-016912m676m67710.1107/S1600536813031504Bis(μ-2-hydroxymethyl-2-methylpropane-1,3-diolato)bis[dichloridotitanium(IV)] diethyl ether disolvateJoyce M. WatersChaohong ShenAlastair J. NielsonThe title complex, [Ti2Cl4{CH3C(CH2O)2(CH2OH)}2], lies across a centre of symmetry with a diethyl ether solvent molecule hydrogen bonded to the –CH2OH groups on either side of it. The TiIV atom is coordinated in a distorted octahedral geometry by a tripodal ligand and two terminal chloride atoms. There are three coordination modes for the tripodal ligand distinguishable on the basis of their very different Ti—O bond lengths. For the terminal alkoxo ligand, the Ti—O distance is 1.760 (1) Å, the asymmetric bridge system has Ti—O bond lengths of 1.911 (1) and 2.048 (1) Å. The Ti—O bond length for the alcohol O atom is the longest at 2.148 (1) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536813031504
collection DOAJ
language English
format Article
sources DOAJ
author Joyce M. Waters
Chaohong Shen
Alastair J. Nielson
spellingShingle Joyce M. Waters
Chaohong Shen
Alastair J. Nielson
Bis(μ-2-hydroxymethyl-2-methylpropane-1,3-diolato)bis[dichloridotitanium(IV)] diethyl ether disolvate
Acta Crystallographica Section E
author_facet Joyce M. Waters
Chaohong Shen
Alastair J. Nielson
author_sort Joyce M. Waters
title Bis(μ-2-hydroxymethyl-2-methylpropane-1,3-diolato)bis[dichloridotitanium(IV)] diethyl ether disolvate
title_short Bis(μ-2-hydroxymethyl-2-methylpropane-1,3-diolato)bis[dichloridotitanium(IV)] diethyl ether disolvate
title_full Bis(μ-2-hydroxymethyl-2-methylpropane-1,3-diolato)bis[dichloridotitanium(IV)] diethyl ether disolvate
title_fullStr Bis(μ-2-hydroxymethyl-2-methylpropane-1,3-diolato)bis[dichloridotitanium(IV)] diethyl ether disolvate
title_full_unstemmed Bis(μ-2-hydroxymethyl-2-methylpropane-1,3-diolato)bis[dichloridotitanium(IV)] diethyl ether disolvate
title_sort bis(μ-2-hydroxymethyl-2-methylpropane-1,3-diolato)bis[dichloridotitanium(iv)] diethyl ether disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-12-01
description The title complex, [Ti2Cl4{CH3C(CH2O)2(CH2OH)}2], lies across a centre of symmetry with a diethyl ether solvent molecule hydrogen bonded to the –CH2OH groups on either side of it. The TiIV atom is coordinated in a distorted octahedral geometry by a tripodal ligand and two terminal chloride atoms. There are three coordination modes for the tripodal ligand distinguishable on the basis of their very different Ti—O bond lengths. For the terminal alkoxo ligand, the Ti—O distance is 1.760 (1) Å, the asymmetric bridge system has Ti—O bond lengths of 1.911 (1) and 2.048 (1) Å. The Ti—O bond length for the alcohol O atom is the longest at 2.148 (1) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813031504
work_keys_str_mv AT joycemwaters bis9562hydroxymethyl2methylpropane13diolatobisdichloridotitaniumivdiethyletherdisolvate
AT chaohongshen bis9562hydroxymethyl2methylpropane13diolatobisdichloridotitaniumivdiethyletherdisolvate
AT alastairjnielson bis9562hydroxymethyl2methylpropane13diolatobisdichloridotitaniumivdiethyletherdisolvate
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