Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II)

Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II)

In the title complex, [Cd(C2F3O2)(NO3)(C10H8N2)2], the Cd(II) ion is heptacoordinated by two chelating 2,2′-bipyridyl ligands [Cd...N 2.370 (6)–2.416 (6) Å], one carboxylate O atom [Cd...O 2.290 (6)&...

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Main Authors: Wenzeng Duan, Junshan Sun, Yudao Ma, Rentao Wu
Format: Article
Language:English
Published: International Union of Crystallography 2009-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809016717
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spelling doaj-cc5e0c346146465ba4d90414014a1fca2020-11-25T02:31:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-06-01656m635m63510.1107/S1600536809016717Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II)Wenzeng DuanJunshan SunYudao MaRentao WuIn the title complex, [Cd(C2F3O2)(NO3)(C10H8N2)2], the Cd(II) ion is heptacoordinated by two chelating 2,2′-bipyridyl ligands [Cd...N 2.370 (6)–2.416 (6) Å], one carboxylate O atom [Cd...O 2.290 (6) Å] from the trifluoroacetate ligand and two O atoms [Cd...O 2.386 (6), 2.633 (6) Å] from a chelating nitrate anion. The trifluoromethyl fragment is rotationally disordered between two orientations in a 0.640 (7):0.360 (7) ratio. In the crystal, weak intermolecular C—H...O hydrogen bonds contribute to the crystal packing stability. http://scripts.iucr.org/cgi-bin/paper?S1600536809016717
collection DOAJ
language English
format Article
sources DOAJ
author Wenzeng Duan
Junshan Sun
Yudao Ma
Rentao Wu
spellingShingle Wenzeng Duan
Junshan Sun
Yudao Ma
Rentao Wu
Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II)
Acta Crystallographica Section E
author_facet Wenzeng Duan
Junshan Sun
Yudao Ma
Rentao Wu
author_sort Wenzeng Duan
title Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II)
title_short Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II)
title_full Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II)
title_fullStr Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II)
title_full_unstemmed Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II)
title_sort bis(2,2′-bipyridyl-κ2n,n′)(nitrato-κ2o,o′)(trifluoroacetato-κo)cadmium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-06-01
description In the title complex, [Cd(C2F3O2)(NO3)(C10H8N2)2], the Cd(II) ion is heptacoordinated by two chelating 2,2′-bipyridyl ligands [Cd...N 2.370 (6)–2.416 (6) Å], one carboxylate O atom [Cd...O 2.290 (6) Å] from the trifluoroacetate ligand and two O atoms [Cd...O 2.386 (6), 2.633 (6) Å] from a chelating nitrate anion. The trifluoromethyl fragment is rotationally disordered between two orientations in a 0.640 (7):0.360 (7) ratio. In the crystal, weak intermolecular C—H...O hydrogen bonds contribute to the crystal packing stability.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809016717
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AT junshansun bis22amp8242bipyridylamp9542nnamp8242nitratoamp9542ooamp8242trifluoroacetatoamp954ocadmiumii
AT yudaoma bis22amp8242bipyridylamp9542nnamp8242nitratoamp9542ooamp8242trifluoroacetatoamp954ocadmiumii
AT rentaowu bis22amp8242bipyridylamp9542nnamp8242nitratoamp9542ooamp8242trifluoroacetatoamp954ocadmiumii
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