μ-4,4′-Diazenediyldiphthalato-κ2O2:O2′-bis[pentaaquamanganese(II)] tetrahydrate

μ-4,4′-Diazenediyldiphthalato-κ2O2:O2′-bis[pentaaquamanganese(II)] tetrahydrate

The dinuclear complex in the title compound, [Mn2(C16H6N2O8)(H2O)10]·4H2O, lies on an inversion center. Two delocalized carboxylate groups are each connected in a monodentate fashion to two similar pentaaquamanganese units, whereas the other two localized carboxylate groups are uncoordinate...

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Bibliographic Details
Main Authors: Jian-Wei Bai, Jun Wang, Yang Hou, Bao-Zhong Zhao, Qiang Fu
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807061314
Description
Summary:The dinuclear complex in the title compound, [Mn2(C16H6N2O8)(H2O)10]·4H2O, lies on an inversion center. Two delocalized carboxylate groups are each connected in a monodentate fashion to two similar pentaaquamanganese units, whereas the other two localized carboxylate groups are uncoordinated. The metal ion has octahedral coordination, with the O atom of a carboxylate group and three coordinated water molecules forming the equatorial plane [Mn—OCOO = 2.143 (4) Å] and two water molecules occupying the axial positions. The architecture is further consolidated by extensive hydrogen bonds for which coordinated water molecules serve as donors or acceptors.
ISSN:1600-5368

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