catena-Poly[[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-[3,6-bis(4-pyridyl)-1,2,4,5-tetrazine]] acetonitrile disolvate]

catena-Poly[[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-[3,6-bis(4-pyridyl)-1,2,4,5-tetrazine]] acetonitrile disolvate]

The title compound, {[Cu2I2(C12H8N6)(C18H15P)2]·2CH3CN}n, contains centrosymmetric dinuclear Cu2I2(PPh3)2 units bridged by 3,6-bis(4-pyridyl)-1,2,4,5-tetrazine ligands lying also across crystallographic inversion centers, giving a chain structure in the ab plane. The distorted tetrahedr...

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Main Author: Jinfang Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810042807
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spelling doaj-cbfb1fbb80604f97baa84583db2c1fff2020-11-25T02:14:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1480m148010.1107/S1600536810042807catena-Poly[[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-[3,6-bis(4-pyridyl)-1,2,4,5-tetrazine]] acetonitrile disolvate]Jinfang ZhangThe title compound, {[Cu2I2(C12H8N6)(C18H15P)2]·2CH3CN}n, contains centrosymmetric dinuclear Cu2I2(PPh3)2 units bridged by 3,6-bis(4-pyridyl)-1,2,4,5-tetrazine ligands lying also across crystallographic inversion centers, giving a chain structure in the ab plane. The distorted tetrahedral CuI atoms in the dinuclear unit are coordinated by two bridging iodide anions, one pyridine N atom from the substituted tetrazine ligand and one terminal triphenylphosphine P-atom donor. The Cu...Cu distance is 2.8293 (12) Å, implying a weak Cu...Cu interaction. http://scripts.iucr.org/cgi-bin/paper?S1600536810042807
collection DOAJ
language English
format Article
sources DOAJ
author Jinfang Zhang
spellingShingle Jinfang Zhang
catena-Poly[[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-[3,6-bis(4-pyridyl)-1,2,4,5-tetrazine]] acetonitrile disolvate]
Acta Crystallographica Section E
author_facet Jinfang Zhang
author_sort Jinfang Zhang
title catena-Poly[[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-[3,6-bis(4-pyridyl)-1,2,4,5-tetrazine]] acetonitrile disolvate]
title_short catena-Poly[[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-[3,6-bis(4-pyridyl)-1,2,4,5-tetrazine]] acetonitrile disolvate]
title_full catena-Poly[[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-[3,6-bis(4-pyridyl)-1,2,4,5-tetrazine]] acetonitrile disolvate]
title_fullStr catena-Poly[[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-[3,6-bis(4-pyridyl)-1,2,4,5-tetrazine]] acetonitrile disolvate]
title_full_unstemmed catena-Poly[[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-[3,6-bis(4-pyridyl)-1,2,4,5-tetrazine]] acetonitrile disolvate]
title_sort catena-poly[[[(triphenylphosphane)copper(i)]-di-μ-iodido-[(triphenylphosphane)copper(i)]-μ-[3,6-bis(4-pyridyl)-1,2,4,5-tetrazine]] acetonitrile disolvate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-11-01
description The title compound, {[Cu2I2(C12H8N6)(C18H15P)2]·2CH3CN}n, contains centrosymmetric dinuclear Cu2I2(PPh3)2 units bridged by 3,6-bis(4-pyridyl)-1,2,4,5-tetrazine ligands lying also across crystallographic inversion centers, giving a chain structure in the ab plane. The distorted tetrahedral CuI atoms in the dinuclear unit are coordinated by two bridging iodide anions, one pyridine N atom from the substituted tetrazine ligand and one terminal triphenylphosphine P-atom donor. The Cu...Cu distance is 2.8293 (12) Å, implying a weak Cu...Cu interaction.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810042807
work_keys_str_mv AT jinfangzhang catenapolytriphenylphosphanecopperidiamp956iodidotriphenylphosphanecopperiamp95636bis4pyridyl1245tetrazineacetonitriledisolvate
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