Modified Ferrocenes as Primary Driers for Formulations of Alkyd Paints

The effect of modification of benzoylferrocene periphery on catalytic activity toward drying of alkyd resins has been investigated by the combination of experimental techniques. A series of substituted ferrocenes have been synthesized and characterized by analytical and spectroscopic tools including...

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Main Authors:	Jan Honzíček, Tatiana Fedorova, Jaromír Vinklárek, Tomáš Mikysek, Ivana Císařová
Format:	Article
Language:	English
Published:	MDPI AG 2020-09-01
Series:	Coatings
Subjects:	ferrocene air-drying paint alkyd drier cobalt replacement X-ray diffraction
Online Access:	https://www.mdpi.com/2079-6412/10/9/873

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record_format	Article
spelling	doaj-cbbc4147f4b843729425b4110586821f2020-11-25T03:56:55ZengMDPI AGCoatings2079-64122020-09-011087387310.3390/coatings10090873Modified Ferrocenes as Primary Driers for Formulations of Alkyd PaintsJan Honzíček0Tatiana Fedorova1Jaromír Vinklárek2Tomáš Mikysek3Ivana Císařová4Institute of Chemistry and Technology of Macromolecular Materials, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech RepublicInstitute of Chemistry and Technology of Macromolecular Materials, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech RepublicDepartment of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech RepublicDepartment of Analytical Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech RepublicDepartment of Inorganic Chemistry, Faculty of Science, Charles University in Prague, Hlavova 2030/8, 128 43 Prague 2, Czech RepublicThe effect of modification of benzoylferrocene periphery on catalytic activity toward drying of alkyd resins has been investigated by the combination of experimental techniques. A series of substituted ferrocenes have been synthesized and characterized by analytical and spectroscopic tools including X-ray diffraction analysis on single crystals. The electrochemical behavior of the ferrocene derivatives has been elucidated by cyclic voltammetry and rotation disk voltammetry. The activity toward room temperature curing of alkyd resin has been evaluated by standard mechanical tests on coated plates, which enabled to establish a structure/catalytic activity relationship. Fast drying of test coatings has been observed for formulations of (3-methoxybenzoyl) ferrocene. Time-resolved infrared spectroscopy in combination with attenuated total reflectance sampling technique enabled to reveal the kinetic origin of the improved performance for this ferrocene derivative.https://www.mdpi.com/2079-6412/10/9/873ferroceneair-drying paintalkyddriercobalt replacementX-ray diffraction
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Jan Honzíček Tatiana Fedorova Jaromír Vinklárek Tomáš Mikysek Ivana Císařová
spellingShingle	Jan Honzíček Tatiana Fedorova Jaromír Vinklárek Tomáš Mikysek Ivana Císařová Modified Ferrocenes as Primary Driers for Formulations of Alkyd Paints Coatings ferrocene air-drying paint alkyd drier cobalt replacement X-ray diffraction
author_facet	Jan Honzíček Tatiana Fedorova Jaromír Vinklárek Tomáš Mikysek Ivana Císařová
author_sort	Jan Honzíček
title	Modified Ferrocenes as Primary Driers for Formulations of Alkyd Paints
title_short	Modified Ferrocenes as Primary Driers for Formulations of Alkyd Paints
title_full	Modified Ferrocenes as Primary Driers for Formulations of Alkyd Paints
title_fullStr	Modified Ferrocenes as Primary Driers for Formulations of Alkyd Paints
title_full_unstemmed	Modified Ferrocenes as Primary Driers for Formulations of Alkyd Paints
title_sort	modified ferrocenes as primary driers for formulations of alkyd paints
publisher	MDPI AG
series	Coatings
issn	2079-6412
publishDate	2020-09-01
description	The effect of modification of benzoylferrocene periphery on catalytic activity toward drying of alkyd resins has been investigated by the combination of experimental techniques. A series of substituted ferrocenes have been synthesized and characterized by analytical and spectroscopic tools including X-ray diffraction analysis on single crystals. The electrochemical behavior of the ferrocene derivatives has been elucidated by cyclic voltammetry and rotation disk voltammetry. The activity toward room temperature curing of alkyd resin has been evaluated by standard mechanical tests on coated plates, which enabled to establish a structure/catalytic activity relationship. Fast drying of test coatings has been observed for formulations of (3-methoxybenzoyl) ferrocene. Time-resolved infrared spectroscopy in combination with attenuated total reflectance sampling technique enabled to reveal the kinetic origin of the improved performance for this ferrocene derivative.
topic	ferrocene air-drying paint alkyd drier cobalt replacement X-ray diffraction
url	https://www.mdpi.com/2079-6412/10/9/873
work_keys_str_mv	AT janhonzicek modifiedferrocenesasprimarydriersforformulationsofalkydpaints AT tatianafedorova modifiedferrocenesasprimarydriersforformulationsofalkydpaints AT jaromirvinklarek modifiedferrocenesasprimarydriersforformulationsofalkydpaints AT tomasmikysek modifiedferrocenesasprimarydriersforformulationsofalkydpaints AT ivanacisarova modifiedferrocenesasprimarydriersforformulationsofalkydpaints
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Modified Ferrocenes as Primary Driers for Formulations of Alkyd Paints

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