<b>Synthesis of 2,3-unsaturated furanic hex- and pent-enopyranoside employing the ferrier rearrangement</b>

Glycosidation of various glycals with furanic alcohols in presence of catalytic amount of ceric(IV) ammonium nitrate under neutral condition or using Lewis acid-catalysed proceeds smoothly to afford the corresponding 2,3-unsaturated glycosides in good yields. In the hexose series predominantly &...

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Main Authors:	Soro Yaya, Siaka Sorho, Louis Cottier, Gérard Descotes
Format:	Article
Language:	English
Published:	Chemical Society of Ethiopia 2005-12-01
Series:	Bulletin of the Chemical Society of Ethiopia
Subjects:	Ferrier rearrangement Furanic alcohols Glycosides Ceric(IV) ammonium nitrate Lewis acid catalyst
Online Access:	http://www.ajol.info/index.php/bcse/article/view/21129

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spelling	doaj-cbb8f2db1211429ca308ac209e3b80192020-11-24T22:44:27ZengChemical Society of EthiopiaBulletin of the Chemical Society of Ethiopia1011-39241726-801X2005-12-01192233241<b>Synthesis of 2,3-unsaturated furanic hex- and pent-enopyranoside employing the ferrier rearrangement</b>Soro YayaSiaka SorhoLouis CottierGérard DescotesGlycosidation of various glycals with furanic alcohols in presence of catalytic amount of ceric(IV) ammonium nitrate under neutral condition or using Lewis acid-catalysed proceeds smoothly to afford the corresponding 2,3-unsaturated glycosides in good yields. In the hexose series predominantly α-D-anomers resulted while β-D-anomers are predominant in the pentose serie.http://www.ajol.info/index.php/bcse/article/view/21129Ferrier rearrangementFuranic alcoholsGlycosidesCeric(IV) ammonium nitrateLewis acid catalyst
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Soro Yaya Siaka Sorho Louis Cottier Gérard Descotes
spellingShingle	Soro Yaya Siaka Sorho Louis Cottier Gérard Descotes <b>Synthesis of 2,3-unsaturated furanic hex- and pent-enopyranoside employing the ferrier rearrangement</b> Bulletin of the Chemical Society of Ethiopia Ferrier rearrangement Furanic alcohols Glycosides Ceric(IV) ammonium nitrate Lewis acid catalyst
author_facet	Soro Yaya Siaka Sorho Louis Cottier Gérard Descotes
author_sort	Soro Yaya
title	<b>Synthesis of 2,3-unsaturated furanic hex- and pent-enopyranoside employing the ferrier rearrangement</b>
title_short	<b>Synthesis of 2,3-unsaturated furanic hex- and pent-enopyranoside employing the ferrier rearrangement</b>
title_full	<b>Synthesis of 2,3-unsaturated furanic hex- and pent-enopyranoside employing the ferrier rearrangement</b>
title_fullStr	<b>Synthesis of 2,3-unsaturated furanic hex- and pent-enopyranoside employing the ferrier rearrangement</b>
title_full_unstemmed	<b>Synthesis of 2,3-unsaturated furanic hex- and pent-enopyranoside employing the ferrier rearrangement</b>
title_sort	<b>synthesis of 2,3-unsaturated furanic hex- and pent-enopyranoside employing the ferrier rearrangement</b>
publisher	Chemical Society of Ethiopia
series	Bulletin of the Chemical Society of Ethiopia
issn	1011-3924 1726-801X
publishDate	2005-12-01
description	Glycosidation of various glycals with furanic alcohols in presence of catalytic amount of ceric(IV) ammonium nitrate under neutral condition or using Lewis acid-catalysed proceeds smoothly to afford the corresponding 2,3-unsaturated glycosides in good yields. In the hexose series predominantly α-D-anomers resulted while β-D-anomers are predominant in the pentose serie.
topic	Ferrier rearrangement Furanic alcohols Glycosides Ceric(IV) ammonium nitrate Lewis acid catalyst
url	http://www.ajol.info/index.php/bcse/article/view/21129
work_keys_str_mv	AT soroyaya bsynthesisof23unsaturatedfuranichexandpentenopyranosideemployingtheferrierrearrangementb AT siakasorho bsynthesisof23unsaturatedfuranichexandpentenopyranosideemployingtheferrierrearrangementb AT louiscottier bsynthesisof23unsaturatedfuranichexandpentenopyranosideemployingtheferrierrearrangementb AT gerarddescotes bsynthesisof23unsaturatedfuranichexandpentenopyranosideemployingtheferrierrearrangementb
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<b>Synthesis of 2,3-unsaturated furanic hex- and pent-enopyranoside employing the ferrier rearrangement</b>

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