2-Amino-4-(4-fluorophenyl)-6-methoxy-4H-benzo[h]chromene-3-carbonitrile
In the title molecule, C21H15FN2O2, the dihedral angle between the fluoro-substituted benzene ring and the mean plane of the 4H-benzo[h]chromene ring system [maximum deviation = 0.109 (2) Å] is 83.35 (7)°. The pyran ring adopts a sl...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-06-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812023021 |
| id |
doaj-cb56b5f5476040ec8526785da9f09514 |
|---|---|
| record_format |
Article |
| spelling |
doaj-cb56b5f5476040ec8526785da9f095142020-11-25T01:22:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686o1934o193510.1107/S16005368120230212-Amino-4-(4-fluorophenyl)-6-methoxy-4H-benzo[h]chromene-3-carbonitrileAl-Anood M. Al-DiesAbdel-Galil E. AmrAhmed M. El-AgrodyTze Shyang ChiaHoong-Kun FunIn the title molecule, C21H15FN2O2, the dihedral angle between the fluoro-substituted benzene ring and the mean plane of the 4H-benzo[h]chromene ring system [maximum deviation = 0.109 (2) Å] is 83.35 (7)°. The pyran ring adopts a slight sofa conformation with the tertiary C(H) atom forming the flap. The methoxy group is slightly twisted from the attached benzene ring of the 4H-benzo[h]chromene moiety [C—O—C—C = −4.3 (3)°]. In the crystal, molecules are linked by intermolecular N—H...N hydrogen bonds into infinite wave-like chains along the b axis. The crystal packing is further stabilized by π–π interactions [centroid–centroid distance = 3.7713 (9) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536812023021 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Al-Anood M. Al-Dies Abdel-Galil E. Amr Ahmed M. El-Agrody Tze Shyang Chia Hoong-Kun Fun |
| spellingShingle |
Al-Anood M. Al-Dies Abdel-Galil E. Amr Ahmed M. El-Agrody Tze Shyang Chia Hoong-Kun Fun 2-Amino-4-(4-fluorophenyl)-6-methoxy-4H-benzo[h]chromene-3-carbonitrile Acta Crystallographica Section E |
| author_facet |
Al-Anood M. Al-Dies Abdel-Galil E. Amr Ahmed M. El-Agrody Tze Shyang Chia Hoong-Kun Fun |
| author_sort |
Al-Anood M. Al-Dies |
| title |
2-Amino-4-(4-fluorophenyl)-6-methoxy-4H-benzo[h]chromene-3-carbonitrile |
| title_short |
2-Amino-4-(4-fluorophenyl)-6-methoxy-4H-benzo[h]chromene-3-carbonitrile |
| title_full |
2-Amino-4-(4-fluorophenyl)-6-methoxy-4H-benzo[h]chromene-3-carbonitrile |
| title_fullStr |
2-Amino-4-(4-fluorophenyl)-6-methoxy-4H-benzo[h]chromene-3-carbonitrile |
| title_full_unstemmed |
2-Amino-4-(4-fluorophenyl)-6-methoxy-4H-benzo[h]chromene-3-carbonitrile |
| title_sort |
2-amino-4-(4-fluorophenyl)-6-methoxy-4h-benzo[h]chromene-3-carbonitrile |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-06-01 |
| description |
In the title molecule, C21H15FN2O2, the dihedral angle between the fluoro-substituted benzene ring and the mean plane of the 4H-benzo[h]chromene ring system [maximum deviation = 0.109 (2) Å] is 83.35 (7)°. The pyran ring adopts a slight sofa conformation with the tertiary C(H) atom forming the flap. The methoxy group is slightly twisted from the attached benzene ring of the 4H-benzo[h]chromene moiety [C—O—C—C = −4.3 (3)°]. In the crystal, molecules are linked by intermolecular N—H...N hydrogen bonds into infinite wave-like chains along the b axis. The crystal packing is further stabilized by π–π interactions [centroid–centroid distance = 3.7713 (9) Å]. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812023021 |
| work_keys_str_mv |
AT alanoodmaldies 2amino44fluorophenyl6methoxy4hbenzohchromene3carbonitrile AT abdelgalileamr 2amino44fluorophenyl6methoxy4hbenzohchromene3carbonitrile AT ahmedmelagrody 2amino44fluorophenyl6methoxy4hbenzohchromene3carbonitrile AT tzeshyangchia 2amino44fluorophenyl6methoxy4hbenzohchromene3carbonitrile AT hoongkunfun 2amino44fluorophenyl6methoxy4hbenzohchromene3carbonitrile |
| _version_ |
1725124430489714688 |