Bis[1,3-bis(diphenylphosphino)propane-κ2P:P′]silver(I) bis(chlorodifluoroacetato-κO)triphenylstannate(IV)

Bis[1,3-bis(diphenylphosphino)propane-κ2P:P′]silver(I) bis(chlorodifluoroacetato-κO)triphenylstannate(IV)

In the title salt, [Ag(C27H26P2)2][Sn(C6H5)3(C2ClF2O2)], the AgI atom exists in a tetrahedral coordination geometry formed by four P atoms [Ag—P = 2.460 (1)–2.501 (1) Å], whereas the SnIV atom exists in a trans-trigonal–bipyramidal...

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Bibliographic Details
Main Authors: Seik Weng Ng, Kong Mun Lo, Yin Yin Teo
Format: Article
Language:English
Published: International Union of Crystallography 2008-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808010763
Description
Summary:In the title salt, [Ag(C27H26P2)2][Sn(C6H5)3(C2ClF2O2)], the AgI atom exists in a tetrahedral coordination geometry formed by four P atoms [Ag—P = 2.460 (1)–2.501 (1) Å], whereas the SnIV atom exists in a trans-trigonal–bipyramidal coordination geometry formed by two O [Sn—O = 2.208 (3) and 2.233 (3) Å] and three C atoms [Sn—C = 2.115 (4)–2.128 (4) Å;(Σ C—Sn—C)= 360.0 (6)°].
ISSN:1600-5368

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