[2-(Diphenylphosphanyl)benzenethiolato-κ2P,S](pyridine-2-thiolato-κS)(triphenylphosphine-κP)palladium(II)

[2-(Diphenylphosphanyl)benzenethiolato-κ2P,S](pyridine-2-thiolato-κS)(triphenylphosphine-κP)palladium(II)

In the title compound, [Pd(C5H4NS)(C18H14PS)(C18H15P)], the PdII atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenylphosphanyl)benzenethiolate ligand and the other two by a P atom from a triphenylphosphine ligand and an S atom f...

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Main Authors: Raúl Ríos-Sanchez, Simón Hernández-Ortega, David Morales-Morales, Alcives Avila-Sorrosa
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681003357X
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spelling doaj-ca7eabb56a424b0ba7e8e4fbcf65dd1f2020-11-24T21:56:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1170m117110.1107/S160053681003357X[2-(Diphenylphosphanyl)benzenethiolato-κ2P,S](pyridine-2-thiolato-κS)(triphenylphosphine-κP)palladium(II)Raúl Ríos-SanchezSimón Hernández-OrtegaDavid Morales-MoralesAlcives Avila-SorrosaIn the title compound, [Pd(C5H4NS)(C18H14PS)(C18H15P)], the PdII atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenylphosphanyl)benzenethiolate ligand and the other two by a P atom from a triphenylphosphine ligand and an S atom from a pyridine-2-thiolate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and intermolecular C—H...π and π–π interactions are observed. The pyridyl ring is equally disordered over two positions. http://scripts.iucr.org/cgi-bin/paper?S160053681003357X
collection DOAJ
language English
format Article
sources DOAJ
author Raúl Ríos-Sanchez
Simón Hernández-Ortega
David Morales-Morales
Alcives Avila-Sorrosa
spellingShingle Raúl Ríos-Sanchez
Simón Hernández-Ortega
David Morales-Morales
Alcives Avila-Sorrosa
[2-(Diphenylphosphanyl)benzenethiolato-κ2P,S](pyridine-2-thiolato-κS)(triphenylphosphine-κP)palladium(II)
Acta Crystallographica Section E
author_facet Raúl Ríos-Sanchez
Simón Hernández-Ortega
David Morales-Morales
Alcives Avila-Sorrosa
author_sort Raúl Ríos-Sanchez
title [2-(Diphenylphosphanyl)benzenethiolato-κ2P,S](pyridine-2-thiolato-κS)(triphenylphosphine-κP)palladium(II)
title_short [2-(Diphenylphosphanyl)benzenethiolato-κ2P,S](pyridine-2-thiolato-κS)(triphenylphosphine-κP)palladium(II)
title_full [2-(Diphenylphosphanyl)benzenethiolato-κ2P,S](pyridine-2-thiolato-κS)(triphenylphosphine-κP)palladium(II)
title_fullStr [2-(Diphenylphosphanyl)benzenethiolato-κ2P,S](pyridine-2-thiolato-κS)(triphenylphosphine-κP)palladium(II)
title_full_unstemmed [2-(Diphenylphosphanyl)benzenethiolato-κ2P,S](pyridine-2-thiolato-κS)(triphenylphosphine-κP)palladium(II)
title_sort [2-(diphenylphosphanyl)benzenethiolato-κ2p,s](pyridine-2-thiolato-κs)(triphenylphosphine-κp)palladium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-09-01
description In the title compound, [Pd(C5H4NS)(C18H14PS)(C18H15P)], the PdII atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenylphosphanyl)benzenethiolate ligand and the other two by a P atom from a triphenylphosphine ligand and an S atom from a pyridine-2-thiolate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and intermolecular C—H...π and π–π interactions are observed. The pyridyl ring is equally disordered over two positions.
url http://scripts.iucr.org/cgi-bin/paper?S160053681003357X
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AT davidmoralesmorales 2diphenylphosphanylbenzenethiolatoamp9542pspyridine2thiolatoamp954striphenylphosphineamp954ppalladiumii
AT alcivesavilasorrosa 2diphenylphosphanylbenzenethiolatoamp9542pspyridine2thiolatoamp954striphenylphosphineamp954ppalladiumii
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