P,P-Diphenyl-N-(1,1,2,2-tetraphenyl-1λ5-diphosphanylidene)phosphinous amide

P,P-Diphenyl-N-(1,1,2,2-tetraphenyl-1λ5-diphosphanylidene)phosphinous amide

The title compound, C36H30NP3, a structural isomer of tris(diphenylphosphino)amine, was unexpectedly isolated as the sole phosphorus-containing product from the reaction of Mg[N(PPh2)2]2(THF)2 (THF is tetrahydrofuran) with CO2. Its identity was confirmed by 31P NMR spectroscopy and single-crystal X-...

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Main Authors: Diane A. Dickie, Richard A. Kemp
Format: Article
Language:English
Published: International Union of Crystallography 2008-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808020412
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spelling doaj-c98c7c1869cc450c8a8d7b67b9182e972020-11-25T01:37:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-08-01648o1449o144910.1107/S1600536808020412P,P-Diphenyl-N-(1,1,2,2-tetraphenyl-1λ5-diphosphanylidene)phosphinous amideDiane A. DickieRichard A. KempThe title compound, C36H30NP3, a structural isomer of tris(diphenylphosphino)amine, was unexpectedly isolated as the sole phosphorus-containing product from the reaction of Mg[N(PPh2)2]2(THF)2 (THF is tetrahydrofuran) with CO2. Its identity was confirmed by 31P NMR spectroscopy and single-crystal X-ray diffraction. The geometry at the two P(III) atoms is trigonal pyramidal, while the P(V) atom adopts a distorted tetrahedral geometry.http://scripts.iucr.org/cgi-bin/paper?S1600536808020412
collection DOAJ
language English
format Article
sources DOAJ
author Diane A. Dickie
Richard A. Kemp
spellingShingle Diane A. Dickie
Richard A. Kemp
P,P-Diphenyl-N-(1,1,2,2-tetraphenyl-1λ5-diphosphanylidene)phosphinous amide
Acta Crystallographica Section E
author_facet Diane A. Dickie
Richard A. Kemp
author_sort Diane A. Dickie
title P,P-Diphenyl-N-(1,1,2,2-tetraphenyl-1λ5-diphosphanylidene)phosphinous amide
title_short P,P-Diphenyl-N-(1,1,2,2-tetraphenyl-1λ5-diphosphanylidene)phosphinous amide
title_full P,P-Diphenyl-N-(1,1,2,2-tetraphenyl-1λ5-diphosphanylidene)phosphinous amide
title_fullStr P,P-Diphenyl-N-(1,1,2,2-tetraphenyl-1λ5-diphosphanylidene)phosphinous amide
title_full_unstemmed P,P-Diphenyl-N-(1,1,2,2-tetraphenyl-1λ5-diphosphanylidene)phosphinous amide
title_sort p,p-diphenyl-n-(1,1,2,2-tetraphenyl-1λ5-diphosphanylidene)phosphinous amide
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-08-01
description The title compound, C36H30NP3, a structural isomer of tris(diphenylphosphino)amine, was unexpectedly isolated as the sole phosphorus-containing product from the reaction of Mg[N(PPh2)2]2(THF)2 (THF is tetrahydrofuran) with CO2. Its identity was confirmed by 31P NMR spectroscopy and single-crystal X-ray diffraction. The geometry at the two P(III) atoms is trigonal pyramidal, while the P(V) atom adopts a distorted tetrahedral geometry.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808020412
work_keys_str_mv AT dianeadickie ppdiphenyln1122tetraphenyl19555diphosphanylidenephosphinousamide
AT richardakemp ppdiphenyln1122tetraphenyl19555diphosphanylidenephosphinousamide
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