P,P-Diphenyl-N-(1,1,2,2-tetraphenyl-1λ5-diphosphanylidene)phosphinous amide
The title compound, C36H30NP3, a structural isomer of tris(diphenylphosphino)amine, was unexpectedly isolated as the sole phosphorus-containing product from the reaction of Mg[N(PPh2)2]2(THF)2 (THF is tetrahydrofuran) with CO2. Its identity was confirmed by 31P NMR spectroscopy and single-crystal X-...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808020412 |
| Summary: | The title compound, C36H30NP3, a structural isomer of tris(diphenylphosphino)amine, was unexpectedly isolated as the sole phosphorus-containing product from the reaction of Mg[N(PPh2)2]2(THF)2 (THF is tetrahydrofuran) with CO2. Its identity was confirmed by 31P NMR spectroscopy and single-crystal X-ray diffraction. The geometry at the two P(III) atoms is trigonal pyramidal, while the P(V) atom adopts a distorted tetrahedral geometry. |
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| ISSN: | 1600-5368 |