(Acetylacetonato-κ2O,O′)aqua[2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ2O,N′]manganese(III)

(Acetylacetonato-κ2O,O′)aqua[2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ2O,N′]manganese(III)

In the title complex, [Mn(C15H11N3O5)(C5H7O2)(H2O)], the MnIII ion has a distorted octahedral coordination geometry. It is coordinated by a phenoxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidate dianion...

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Bibliographic Details
Main Author: Zi-Jing Xiao
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809028177
Description
Summary:In the title complex, [Mn(C15H11N3O5)(C5H7O2)(H2O)], the MnIII ion has a distorted octahedral coordination geometry. It is coordinated by a phenoxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidate dianion, by two O atoms of the acetylacetonate anion and by the O atom of a coordinated water molecule. In the crystal structure, complex molecules are linked into centrosymmetric dimeric units through four intermolecular O—H...O hydrogen bonds involving both H atoms of the coordinated water molecule.
ISSN:1600-5368

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