Synthesis of Some New Mono- and Bis-Polycyclic Aromatic Spiro and Bis-Nonspiro-β-Lactams

Some new mono-and bis-polycyclic aromatic spiro-β-lactams and bis-non spiro-polycyclic aromatic β-lactams have been synthesized from imines derived from anthracene-9-carbaldehyde, 2-naphtaldehyde and a ketene derived from 9H-xanthene-9-carboxylic acid and phenoxyacetic acid by a [2+2] cycloaddition...

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Main Authors: Edris Ebrahimi, Aliasghar Jarrahpour
Format: Article
Language:English
Published: MDPI AG 2010-01-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/15/1/515/
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spelling doaj-c96ae7326d214757b3e5fb012ad4bb642020-11-24T23:44:05ZengMDPI AGMolecules1420-30492010-01-0115151553110.3390/molecules15010515Synthesis of Some New Mono- and Bis-Polycyclic Aromatic Spiro and Bis-Nonspiro-β-LactamsEdris EbrahimiAliasghar JarrahpourSome new mono-and bis-polycyclic aromatic spiro-β-lactams and bis-non spiro-polycyclic aromatic β-lactams have been synthesized from imines derived from anthracene-9-carbaldehyde, 2-naphtaldehyde and a ketene derived from 9H-xanthene-9-carboxylic acid and phenoxyacetic acid by a [2+2] cycloaddition reaction. The cycloadducts were characterized by spectral data, including 1H-NMR, 13C-NMR, IR and elemental analyses. The configurations of some of these mono-spiro-β-lactams were established by X-ray crystal analysis. http://www.mdpi.com/1420-3049/15/1/515/mono- and bis-spiro-β-lactampolycyclic aromatic imine9H-xanthene-9-carboxylic acidphenoxyacetic acid[2+2] cycloadditiontosyl chloride
collection DOAJ
language English
format Article
sources DOAJ
author Edris Ebrahimi
Aliasghar Jarrahpour
spellingShingle Edris Ebrahimi
Aliasghar Jarrahpour
Synthesis of Some New Mono- and Bis-Polycyclic Aromatic Spiro and Bis-Nonspiro-β-Lactams
Molecules
mono- and bis-spiro-β-lactam
polycyclic aromatic imine
9H-xanthene-9-carboxylic acid
phenoxyacetic acid
[2+2] cycloaddition
tosyl chloride
author_facet Edris Ebrahimi
Aliasghar Jarrahpour
author_sort Edris Ebrahimi
title Synthesis of Some New Mono- and Bis-Polycyclic Aromatic Spiro and Bis-Nonspiro-β-Lactams
title_short Synthesis of Some New Mono- and Bis-Polycyclic Aromatic Spiro and Bis-Nonspiro-β-Lactams
title_full Synthesis of Some New Mono- and Bis-Polycyclic Aromatic Spiro and Bis-Nonspiro-β-Lactams
title_fullStr Synthesis of Some New Mono- and Bis-Polycyclic Aromatic Spiro and Bis-Nonspiro-β-Lactams
title_full_unstemmed Synthesis of Some New Mono- and Bis-Polycyclic Aromatic Spiro and Bis-Nonspiro-β-Lactams
title_sort synthesis of some new mono- and bis-polycyclic aromatic spiro and bis-nonspiro-β-lactams
publisher MDPI AG
series Molecules
issn 1420-3049
publishDate 2010-01-01
description Some new mono-and bis-polycyclic aromatic spiro-β-lactams and bis-non spiro-polycyclic aromatic β-lactams have been synthesized from imines derived from anthracene-9-carbaldehyde, 2-naphtaldehyde and a ketene derived from 9H-xanthene-9-carboxylic acid and phenoxyacetic acid by a [2+2] cycloaddition reaction. The cycloadducts were characterized by spectral data, including 1H-NMR, 13C-NMR, IR and elemental analyses. The configurations of some of these mono-spiro-β-lactams were established by X-ray crystal analysis.
topic mono- and bis-spiro-β-lactam
polycyclic aromatic imine
9H-xanthene-9-carboxylic acid
phenoxyacetic acid
[2+2] cycloaddition
tosyl chloride
url http://www.mdpi.com/1420-3049/15/1/515/
work_keys_str_mv AT edrisebrahimi synthesisofsomenewmonoandbispolycyclicaromaticspiroandbisnonspiroblactams
AT aliasgharjarrahpour synthesisofsomenewmonoandbispolycyclicaromaticspiroandbisnonspiroblactams
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