Diastereomeric Amides Derived from Malonic Acid: the Role of Chiral Auxiliaries and of the Nature of Co-Acids in the Mixed Kolbe Electrolyses
Experiments towards the diastereoselective coupling of new malonic acid amides synthesized with commercially available chiral amines [(S)-(+)-1-cyclohexylethylamine and (R)-(+)-1-phenylethylamine] as chiral auxiliaries were performed through Kolbe oxidations [undivided cell, Pt (anode and cathode),...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Sociedade Brasileira de Química
1999-01-01
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| Series: | Journal of the Brazilian Chemical Society |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531999000200014 |