A comparative study on chemiluminescence propperties of some inorganic systems

Chemiluminescence (CL) of selected inorganic reaction systems, generating ultraweak photon emission, has been studied. The kinetics of the systems and their emission spectra have been characterised by measurements with the use of the stationary and the flow methods of CL recording. The systems studi...

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Main Authors:	Marian Elbanowski, Krzysztof Staninski, Malgorzata Kaczmarek, Stefan Lis
Format:	Article
Language:	English
Published:	Hindawi Limited 2003-01-01
Series:	International Journal of Photoenergy
Online Access:	http://dx.doi.org/10.1155/S1110662X03000382

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spelling	doaj-c90152154ab944fe8fc9d6487fa098a72020-11-24T23:44:15ZengHindawi LimitedInternational Journal of Photoenergy1110-662X2003-01-015423924210.1155/S1110662X03000382A comparative study on chemiluminescence propperties of some inorganic systemsMarian Elbanowski0Krzysztof Staninski1Malgorzata Kaczmarek2Stefan Lis3Department of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, Poznań 60-780, PolandDepartment of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, Poznań 60-780, PolandDepartment of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, Poznań 60-780, PolandDepartment of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, Poznań 60-780, PolandChemiluminescence (CL) of selected inorganic reaction systems, generating ultraweak photon emission, has been studied. The kinetics of the systems and their emission spectra have been characterised by measurements with the use of the stationary and the flow methods of CL recording. The systems studied contained cations at different oxidation degree such as Fe2+\3+, Cu+\2+, Co2+\3+, Eu2+\3+, CLO− anions and hydrogen peroxide without organic sensitisers. On the basis of the analysis of the spectra, in particular systems emitters have been identified and mechanisms of the reactions have been proposed. The effect of carbonate and azide ions and propylene carbonate on the yield of CL and spectral characterisation of the systems studied has been evidenced and discussed. A possibility of the application of the systems Eu3+\N3− \H2O2 and Co2+\propylene carbonate\H2O2 for analytical purposes has been considered.http://dx.doi.org/10.1155/S1110662X03000382
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Marian Elbanowski Krzysztof Staninski Malgorzata Kaczmarek Stefan Lis
spellingShingle	Marian Elbanowski Krzysztof Staninski Malgorzata Kaczmarek Stefan Lis A comparative study on chemiluminescence propperties of some inorganic systems International Journal of Photoenergy
author_facet	Marian Elbanowski Krzysztof Staninski Malgorzata Kaczmarek Stefan Lis
author_sort	Marian Elbanowski
title	A comparative study on chemiluminescence propperties of some inorganic systems
title_short	A comparative study on chemiluminescence propperties of some inorganic systems
title_full	A comparative study on chemiluminescence propperties of some inorganic systems
title_fullStr	A comparative study on chemiluminescence propperties of some inorganic systems
title_full_unstemmed	A comparative study on chemiluminescence propperties of some inorganic systems
title_sort	comparative study on chemiluminescence propperties of some inorganic systems
publisher	Hindawi Limited
series	International Journal of Photoenergy
issn	1110-662X
publishDate	2003-01-01
description	Chemiluminescence (CL) of selected inorganic reaction systems, generating ultraweak photon emission, has been studied. The kinetics of the systems and their emission spectra have been characterised by measurements with the use of the stationary and the flow methods of CL recording. The systems studied contained cations at different oxidation degree such as Fe2+\3+, Cu+\2+, Co2+\3+, Eu2+\3+, CLO− anions and hydrogen peroxide without organic sensitisers. On the basis of the analysis of the spectra, in particular systems emitters have been identified and mechanisms of the reactions have been proposed. The effect of carbonate and azide ions and propylene carbonate on the yield of CL and spectral characterisation of the systems studied has been evidenced and discussed. A possibility of the application of the systems Eu3+\N3− \H2O2 and Co2+\propylene carbonate\H2O2 for analytical purposes has been considered.
url	http://dx.doi.org/10.1155/S1110662X03000382
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A comparative study on chemiluminescence propperties of some inorganic systems

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