Synthesis and crystal structure of (1,10-phenanthroline-κ2N,N′)[2-(1H-pyrazol-1-yl)phenyl-κ2N2,C1]iridium(III) hexafluoridophosphate with an unknown number of solvent molecules

Synthesis and crystal structure of (1,10-phenanthroline-κ2N,N′)[2-(1H-pyrazol-1-yl)phenyl-κ2N2,C1]iridium(III) hexafluoridophosphate with an unknown number of solvent molecules

The cationic complex in the title compound, [Ir(C9H7N2)2(C12H8N2)]PF6, comprises two phenylpyrazole (ppz) cyclometallating ligands and one 1,10-phenanthroline (phen) ancillary ligand. The asymmetric unit consists of one [Ir(ppz)2(phen)]+ cation and one [PF6]− counter-ion. The central IrIII ion is si...

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Bibliographic Details
Main Authors: Juxiang Zeng, Guodong Tang, Jun Qian
Format: Article
Language:English
Published: International Union of Crystallography 2020-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cyclometallated iridium complex
1,10-phenanthroline
1-phenylpyrazole
intermolecular hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989020005861

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http://scripts.iucr.org/cgi-bin/paper?S2056989020005861

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