Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2N,O)copper(II)

Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2N,O)copper(II)

In the title compound, [Cu(C10H11BrNO)2], the asymmetric unit consists of one-half of the molecule, the other half being generated by an inversion centre. Hence the CuII cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu—...

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Main Authors: Ali Ourari, Chahinaz Zoubeidi, Sofiane Bouacida, Wassila Derafa, Hocine Merazig
Format: Article
Language:English
Published: International Union of Crystallography 2015-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
copper(II) complex
C—H...π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015001309
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spelling doaj-c80c399ea9f34db4aebdb2fbc93cda3b2020-11-24T22:38:44ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-02-01712m33m3410.1107/S2056989015001309wm5116Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2N,O)copper(II)Ali Ourari0Chahinaz Zoubeidi1Sofiane Bouacida2Wassila Derafa3Hocine Merazig4Laboratoire d'Electrochimie, d'Ingénierie Moléculaire et de Catalyse Redox (LEIMCR), Faculté des Sciences de l'Ingénieur, Université Farhat Abbas, Sétif 19000, AlgeriaLaboratoire d'Electrochimie, d'Ingénierie Moléculaire et de Catalyse Redox (LEIMCR), Faculté des Sciences de l'Ingénieur, Université Farhat Abbas, Sétif 19000, AlgeriaDépartement Sciences de la Matière, Faculté des sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi, AlgeriaLaboratoire d'Electrochimie, d'Ingénierie Moléculaire et de Catalyse Redox (LEIMCR), Faculté des Sciences de l'Ingénieur, Université Farhat Abbas, Sétif 19000, AlgeriaUnité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, CHEMS, Université Constantine 1, 25000 , AlgeriaIn the title compound, [Cu(C10H11BrNO)2], the asymmetric unit consists of one-half of the molecule, the other half being generated by an inversion centre. Hence the CuII cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu—O and Cu—N bond lengths of 1.8786 (19) and 2.009 (2) Å, respectively. In the crystal, individual molecules are packed in alternating zigzag layers parallel to (001). Weak C—H...π interactions exist between the molecules.http://scripts.iucr.org/cgi-bin/paper?S2056989015001309crystal structurecopper(II) complexC—H...π interactions
collection DOAJ
language English
format Article
sources DOAJ
author Ali Ourari
Chahinaz Zoubeidi
Sofiane Bouacida
Wassila Derafa
Hocine Merazig
spellingShingle Ali Ourari
Chahinaz Zoubeidi
Sofiane Bouacida
Wassila Derafa
Hocine Merazig
Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2N,O)copper(II)
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
copper(II) complex
C—H...π interactions
author_facet Ali Ourari
Chahinaz Zoubeidi
Sofiane Bouacida
Wassila Derafa
Hocine Merazig
author_sort Ali Ourari
title Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2N,O)copper(II)
title_short Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2N,O)copper(II)
title_full Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2N,O)copper(II)
title_fullStr Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2N,O)copper(II)
title_full_unstemmed Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2N,O)copper(II)
title_sort crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2n,o)copper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2015-02-01
description In the title compound, [Cu(C10H11BrNO)2], the asymmetric unit consists of one-half of the molecule, the other half being generated by an inversion centre. Hence the CuII cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu—O and Cu—N bond lengths of 1.8786 (19) and 2.009 (2) Å, respectively. In the crystal, individual molecules are packed in alternating zigzag layers parallel to (001). Weak C—H...π interactions exist between the molecules.
topic crystal structure
copper(II) complex
C—H...π interactions
url http://scripts.iucr.org/cgi-bin/paper?S2056989015001309
work_keys_str_mv AT aliourari crystalstructureofbis23bromopropyliminomethylphenolatok2nocopperii
AT chahinazzoubeidi crystalstructureofbis23bromopropyliminomethylphenolatok2nocopperii
AT sofianebouacida crystalstructureofbis23bromopropyliminomethylphenolatok2nocopperii
AT wassiladerafa crystalstructureofbis23bromopropyliminomethylphenolatok2nocopperii
AT hocinemerazig crystalstructureofbis23bromopropyliminomethylphenolatok2nocopperii
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