Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2N,O)copper(II)

Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2N,O)copper(II)

In the title compound, [Cu(C10H11BrNO)2], the asymmetric unit consists of one-half of the molecule, the other half being generated by an inversion centre. Hence the CuII cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu—...

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Bibliographic Details
Main Authors: Ali Ourari, Chahinaz Zoubeidi, Sofiane Bouacida, Wassila Derafa, Hocine Merazig
Format: Article
Language:English
Published: International Union of Crystallography 2015-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
copper(II) complex
C—H...π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015001309
Description
Summary:In the title compound, [Cu(C10H11BrNO)2], the asymmetric unit consists of one-half of the molecule, the other half being generated by an inversion centre. Hence the CuII cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu—O and Cu—N bond lengths of 1.8786 (19) and 2.009 (2) Å, respectively. In the crystal, individual molecules are packed in alternating zigzag layers parallel to (001). Weak C—H...π interactions exist between the molecules.
ISSN:2056-9890

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