Bis(μ-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(II)] N,N-dimethylformamide tetrasolvate

Bis(μ-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(II)] N,N-dimethylformamide tetrasolvate

In the dinuclear title compound, [Zn2(C14H12N3O2S)2Cl2]·4C3H7NO, the two monodeprotonated Schiff base ligands N,O,S:O-chelate to Zn atoms. The formally negatively charged O atom involved in chelation also serves as a bridge. The O, O′, N and S atoms comprise a square, and...

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Main Authors: Kong Wai Tan, Chew Hee Ng, M. Jamil Maah, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2010-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810014522
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spelling doaj-c7fb525a89704c28a25eb551cd50ee832020-11-24T21:32:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-05-01665m569m56910.1107/S1600536810014522Bis(μ-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(II)] N,N-dimethylformamide tetrasolvateKong Wai TanChew Hee NgM. Jamil MaahSeik Weng NgIn the dinuclear title compound, [Zn2(C14H12N3O2S)2Cl2]·4C3H7NO, the two monodeprotonated Schiff base ligands N,O,S:O-chelate to Zn atoms. The formally negatively charged O atom involved in chelation also serves as a bridge. The O, O′, N and S atoms comprise a square, and the Cl atom the apex of a square pyramid surrounding each metal atom. The solvate dimethylformamide molecules, one of which is disordered over two positions in a 3:1 ratio, are hydrogen bonded to the dinuclear molecule. http://scripts.iucr.org/cgi-bin/paper?S1600536810014522
collection DOAJ
language English
format Article
sources DOAJ
author Kong Wai Tan
Chew Hee Ng
M. Jamil Maah
Seik Weng Ng
spellingShingle Kong Wai Tan
Chew Hee Ng
M. Jamil Maah
Seik Weng Ng
Bis(μ-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(II)] N,N-dimethylformamide tetrasolvate
Acta Crystallographica Section E
author_facet Kong Wai Tan
Chew Hee Ng
M. Jamil Maah
Seik Weng Ng
author_sort Kong Wai Tan
title Bis(μ-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(II)] N,N-dimethylformamide tetrasolvate
title_short Bis(μ-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(II)] N,N-dimethylformamide tetrasolvate
title_full Bis(μ-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(II)] N,N-dimethylformamide tetrasolvate
title_fullStr Bis(μ-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(II)] N,N-dimethylformamide tetrasolvate
title_full_unstemmed Bis(μ-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(II)] N,N-dimethylformamide tetrasolvate
title_sort bis(μ-5-hydroxy-2-{[2-(n-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(ii)] n,n-dimethylformamide tetrasolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-05-01
description In the dinuclear title compound, [Zn2(C14H12N3O2S)2Cl2]·4C3H7NO, the two monodeprotonated Schiff base ligands N,O,S:O-chelate to Zn atoms. The formally negatively charged O atom involved in chelation also serves as a bridge. The O, O′, N and S atoms comprise a square, and the Cl atom the apex of a square pyramid surrounding each metal atom. The solvate dimethylformamide molecules, one of which is disordered over two positions in a 3:1 ratio, are hydrogen bonded to the dinuclear molecule.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810014522
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AT chewheeng bisamp9565hydroxy22nphenylthiocarbamoylhydrazin1ylidenemethylphenolatobischloridozinciinndimethylformamidetetrasolvate
AT mjamilmaah bisamp9565hydroxy22nphenylthiocarbamoylhydrazin1ylidenemethylphenolatobischloridozinciinndimethylformamidetetrasolvate
AT seikwengng bisamp9565hydroxy22nphenylthiocarbamoylhydrazin1ylidenemethylphenolatobischloridozinciinndimethylformamidetetrasolvate
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