Bis(μ-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(II)] N,N-dimethylformamide tetrasolvate

Bis(μ-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl}phenolato)bis[chloridozinc(II)] N,N-dimethylformamide tetrasolvate

In the dinuclear title compound, [Zn2(C14H12N3O2S)2Cl2]·4C3H7NO, the two monodeprotonated Schiff base ligands N,O,S:O-chelate to Zn atoms. The formally negatively charged O atom involved in chelation also serves as a bridge. The O, O′, N and S atoms comprise a square, and...

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Bibliographic Details
Main Authors: Kong Wai Tan, Chew Hee Ng, M. Jamil Maah, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2010-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810014522
Description
Summary:In the dinuclear title compound, [Zn2(C14H12N3O2S)2Cl2]·4C3H7NO, the two monodeprotonated Schiff base ligands N,O,S:O-chelate to Zn atoms. The formally negatively charged O atom involved in chelation also serves as a bridge. The O, O′, N and S atoms comprise a square, and the Cl atom the apex of a square pyramid surrounding each metal atom. The solvate dimethylformamide molecules, one of which is disordered over two positions in a 3:1 ratio, are hydrogen bonded to the dinuclear molecule.
ISSN:1600-5368

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