Tetrapotassium heptacyanidomolybdate(III) dihydrate

Tetrapotassium heptacyanidomolybdate(III) dihydrate

The asymmetric unit of the title compound, KI4[MoIII(CN)7]·2H2O, consists of one [Mo(CN)7]4− anion, four K+ cations, and two water molecules. The [MoIII(CN)7]4− anion has a seven-coordinated capped-trigonal-prismatic coordination geometry. The site-occupancy...

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Main Authors: Koji Nakabayashi, Keisuke Tomono, Yoshihide Tsunobuchi, Wataru Kosaka, Shin-ichi Ohkoshi
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809039336
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spelling doaj-c7f6130cf08b452d8ab4eb9609edb7af2020-11-25T01:00:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511i79i8010.1107/S1600536809039336Tetrapotassium heptacyanidomolybdate(III) dihydrateKoji NakabayashiKeisuke TomonoYoshihide TsunobuchiWataru KosakaShin-ichi OhkoshiThe asymmetric unit of the title compound, KI4[MoIII(CN)7]·2H2O, consists of one [Mo(CN)7]4− anion, four K+ cations, and two water molecules. The [MoIII(CN)7]4− anion has a seven-coordinated capped-trigonal-prismatic coordination geometry. The site-occupancy factors of the disordered water molecules were set at 0.90, 0.60 and 0.50. The H-atom positions could not be determined for two of the water molecules. The H atoms of the water with a site-occupancy factor of 0.90 were refined using O—H and H...H distance restraints. http://scripts.iucr.org/cgi-bin/paper?S1600536809039336
collection DOAJ
language English
format Article
sources DOAJ
author Koji Nakabayashi
Keisuke Tomono
Yoshihide Tsunobuchi
Wataru Kosaka
Shin-ichi Ohkoshi
spellingShingle Koji Nakabayashi
Keisuke Tomono
Yoshihide Tsunobuchi
Wataru Kosaka
Shin-ichi Ohkoshi
Tetrapotassium heptacyanidomolybdate(III) dihydrate
Acta Crystallographica Section E
author_facet Koji Nakabayashi
Keisuke Tomono
Yoshihide Tsunobuchi
Wataru Kosaka
Shin-ichi Ohkoshi
author_sort Koji Nakabayashi
title Tetrapotassium heptacyanidomolybdate(III) dihydrate
title_short Tetrapotassium heptacyanidomolybdate(III) dihydrate
title_full Tetrapotassium heptacyanidomolybdate(III) dihydrate
title_fullStr Tetrapotassium heptacyanidomolybdate(III) dihydrate
title_full_unstemmed Tetrapotassium heptacyanidomolybdate(III) dihydrate
title_sort tetrapotassium heptacyanidomolybdate(iii) dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-11-01
description The asymmetric unit of the title compound, KI4[MoIII(CN)7]·2H2O, consists of one [Mo(CN)7]4− anion, four K+ cations, and two water molecules. The [MoIII(CN)7]4− anion has a seven-coordinated capped-trigonal-prismatic coordination geometry. The site-occupancy factors of the disordered water molecules were set at 0.90, 0.60 and 0.50. The H-atom positions could not be determined for two of the water molecules. The H atoms of the water with a site-occupancy factor of 0.90 were refined using O—H and H...H distance restraints.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809039336
work_keys_str_mv AT kojinakabayashi tetrapotassiumheptacyanidomolybdateiiidihydrate
AT keisuketomono tetrapotassiumheptacyanidomolybdateiiidihydrate
AT yoshihidetsunobuchi tetrapotassiumheptacyanidomolybdateiiidihydrate
AT watarukosaka tetrapotassiumheptacyanidomolybdateiiidihydrate
AT shinichiohkoshi tetrapotassiumheptacyanidomolybdateiiidihydrate
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