catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine]

catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine]

In the crystal structure of the title compound, [Fe3(NCS)6(C4H4N2)8]n, each iron(II) cation is coordinated by four N-bonded pyrimidine ligands and two N-bonded thiocyanate anions in a distorted octahedral environment. The asymmetric unit consists of one iron cation located on a crystallographic cent...

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Format: Article
Language:English
Published: International Union of Crystallography 2009-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809005509
id doaj-c7ae9a8d3e7d4fc3aaaa238c26b60af3
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spelling doaj-c7ae9a8d3e7d4fc3aaaa238c26b60af32020-11-25T01:13:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-03-01653m296m29710.1107/S1600536809005509catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine]In the crystal structure of the title compound, [Fe3(NCS)6(C4H4N2)8]n, each iron(II) cation is coordinated by four N-bonded pyrimidine ligands and two N-bonded thiocyanate anions in a distorted octahedral environment. The asymmetric unit consists of one iron cation located on a crystallographic center of inversion, as well as one iron cation, three thiocyanate anions and four pyrimidine ligands occupying general positions. The structure consists of square secondary building units (SBUs) with an Fe atom at each corner, which are μ-N1:N3-bridged by the pyrimidine ligands. The SBUs are linked into infinite chains running in the c-axis direction via common opposite corners. http://scripts.iucr.org/cgi-bin/paper?S1600536809005509
collection DOAJ
language English
format Article
sources DOAJ
title catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine]
spellingShingle catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine]
Acta Crystallographica Section E
title_short catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine]
title_full catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine]
title_fullStr catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine]
title_full_unstemmed catena-Poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(II)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(II)]-di-μ-pyrimidine]
title_sort catena-poly[bis[cis-dipyrimidine-trans-dithiocyanatoiron(ii)]-di-μ-pyrimidine-[trans-dithiocyanatoiron(ii)]-di-μ-pyrimidine]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-03-01
description In the crystal structure of the title compound, [Fe3(NCS)6(C4H4N2)8]n, each iron(II) cation is coordinated by four N-bonded pyrimidine ligands and two N-bonded thiocyanate anions in a distorted octahedral environment. The asymmetric unit consists of one iron cation located on a crystallographic center of inversion, as well as one iron cation, three thiocyanate anions and four pyrimidine ligands occupying general positions. The structure consists of square secondary building units (SBUs) with an Fe atom at each corner, which are μ-N1:N3-bridged by the pyrimidine ligands. The SBUs are linked into infinite chains running in the c-axis direction via common opposite corners.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809005509
_version_ 1725162732004573184

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