cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate

cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate

The metal site in the title compound [MnCl2(C12H12N2)2]·2.5H2O has a distorted octahedral geometry, coordinated by four N atoms of two 5,5′-dimethyl-2,2′-dipyridine ligands and two Cl atoms. Two and a half water molecules of hydration per complex unit are obs...

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Main Authors: Lívia Batista Lopes, Charlane Cimini Corrêa, Renata Diniz
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811021805
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spelling doaj-c781478eb39145a7b480502bd3b20e292020-11-25T00:49:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m906m90710.1107/S1600536811021805cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrateLívia Batista LopesCharlane Cimini CorrêaRenata DinizThe metal site in the title compound [MnCl2(C12H12N2)2]·2.5H2O has a distorted octahedral geometry, coordinated by four N atoms of two 5,5′-dimethyl-2,2′-dipyridine ligands and two Cl atoms. Two and a half water molecules of hydration per complex unit are observed in the crystal structure. The compounds extend along the c axis with O—H...Cl, O—H...O, C—H...Cl and C—H...O hydrogen bonds and π–π interactions [centroid-centroid distance = 3.70 (2) Å] contributing substantially to the crystal packing. The Mn and one of the water O atoms, the latter being half-occupied, are located on special positions, in this case a rotation axis of order 2.http://scripts.iucr.org/cgi-bin/paper?S1600536811021805
collection DOAJ
language English
format Article
sources DOAJ
author Lívia Batista Lopes
Charlane Cimini Corrêa
Renata Diniz
spellingShingle Lívia Batista Lopes
Charlane Cimini Corrêa
Renata Diniz
cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate
Acta Crystallographica Section E
author_facet Lívia Batista Lopes
Charlane Cimini Corrêa
Renata Diniz
author_sort Lívia Batista Lopes
title cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate
title_short cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate
title_full cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate
title_fullStr cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate
title_full_unstemmed cis-Dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(II) 2.5-hydrate
title_sort cis-dichloridobis(5,5′-dimethyl-2,2′-bipyridine)manganese(ii) 2.5-hydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-07-01
description The metal site in the title compound [MnCl2(C12H12N2)2]·2.5H2O has a distorted octahedral geometry, coordinated by four N atoms of two 5,5′-dimethyl-2,2′-dipyridine ligands and two Cl atoms. Two and a half water molecules of hydration per complex unit are observed in the crystal structure. The compounds extend along the c axis with O—H...Cl, O—H...O, C—H...Cl and C—H...O hydrogen bonds and π–π interactions [centroid-centroid distance = 3.70 (2) Å] contributing substantially to the crystal packing. The Mn and one of the water O atoms, the latter being half-occupied, are located on special positions, in this case a rotation axis of order 2.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811021805
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AT charlaneciminicorramp234a cisdichloridobis55amp8242dimethyl22amp8242bipyridinemanganeseii25hydrate
AT renatadiniz cisdichloridobis55amp8242dimethyl22amp8242bipyridinemanganeseii25hydrate
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