Poly[(μ3-5-bromonicotinato)(5-bromonicotinato)copper(II)]
The title coordination polymer, [Cu(C6H3BrNO2)2]n, is composed of two structurally similar two-dimensional coordination polymers (twin layers). Both of them have the same chemical composition but they display different bond lengths and angles. In each layer, two N atoms and four carboxylate O atoms...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809038331 |
| Summary: | The title coordination polymer, [Cu(C6H3BrNO2)2]n, is composed of two structurally similar two-dimensional coordination polymers (twin layers). Both of them have the same chemical composition but they display different bond lengths and angles. In each layer, two N atoms and four carboxylate O atoms from the bridging 5-bromonicotinate ligands and four carboxylate O atoms from the terminal 5-bromonicotinate ligands bind to two CuII atoms to form a dinuclear paddle-wheel-like pattern. Adjacent paddle wheels are further linked by bridging 5-bromonicotinate groups to generate a two-dimensional coordination polymer; neighboring twin-like layers are finally stacked through π–π stacking interactions between adjacent pyridine rings [perpendicular distance of 3.626 (2) Å] in a `sandwich' manner, thus generating a three-dimensional supramolecular structure. |
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| ISSN: | 1600-5368 |