Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–isophthalic acid (1/1)

In the crystal structure of the title co-crystal, C25H32N4O2·C8H6O4, isophthalic acid and [propane-1,3-diylbis(piperidine-4,1-diyl)]bis(pyridin-4-ylmethanone) molecules are connected into supramolecular chains aligned along the c axis by O—H...N hydrogen bonding. These aggregate into supramolecular...

Full description

Bibliographic Details
Main Authors:	Nathan H. Murray, Shannon M. Biros, Robert L. LaDuca
Format:	Article
Language:	English
Published:	International Union of Crystallography 2014-11-01
Series:	Acta Crystallographica Section E
Subjects:	crystal structure isophthalic acid pyridin-4-ylmethanone propane-1,3-diyl supramolecular layers hydrogen bonding
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600536814021679

id	doaj-c707f8485de445f78799faf520a3d308
record_format	Article
spelling	doaj-c707f8485de445f78799faf520a3d3082020-11-25T00:54:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-11-01701129830010.1107/S1600536814021679hg5409Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–isophthalic acid (1/1)Nathan H. Murray0Shannon M. Biros1Robert L. LaDuca2Lyman Briggs College, Department of Chemistry, E-30 Holmes Hall, 919 East Shaw Lane, Michigan State University, East Lansing, MI 48825, USADepartment of Chemistry, Grand Valley State University, Allendale, MI 49401, USALyman Briggs College, Department of Chemistry, E-30 Holmes Hall, 919 East Shaw Lane, Michigan State University, East Lansing, MI 48825, USAIn the crystal structure of the title co-crystal, C25H32N4O2·C8H6O4, isophthalic acid and [propane-1,3-diylbis(piperidine-4,1-diyl)]bis(pyridin-4-ylmethanone) molecules are connected into supramolecular chains aligned along the c axis by O—H...N hydrogen bonding. These aggregate into supramolecular layers oriented parallel to the ac plane by C—H...O interactions. These layers then stack in an ABCD pattern along the b-axis direction by additional C—H...O interactions to give the full three-dimensional crystal structure. The central chain in the dipyridylamide molecule has an anti–gauche conformation.http://scripts.iucr.org/cgi-bin/paper?S1600536814021679crystal structureisophthalic acidpyridin-4-ylmethanonepropane-1,3-diylsupramolecular layershydrogen bonding
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Nathan H. Murray Shannon M. Biros Robert L. LaDuca
spellingShingle	Nathan H. Murray Shannon M. Biros Robert L. LaDuca Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–isophthalic acid (1/1) Acta Crystallographica Section E crystal structure isophthalic acid pyridin-4-ylmethanone propane-1,3-diyl supramolecular layers hydrogen bonding
author_facet	Nathan H. Murray Shannon M. Biros Robert L. LaDuca
author_sort	Nathan H. Murray
title	Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
title_short	Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
title_full	Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
title_fullStr	Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
title_full_unstemmed	Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
title_sort	crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–isophthalic acid (1/1)
publisher	International Union of Crystallography
series	Acta Crystallographica Section E
issn	1600-5368
publishDate	2014-11-01
description	In the crystal structure of the title co-crystal, C25H32N4O2·C8H6O4, isophthalic acid and [propane-1,3-diylbis(piperidine-4,1-diyl)]bis(pyridin-4-ylmethanone) molecules are connected into supramolecular chains aligned along the c axis by O—H...N hydrogen bonding. These aggregate into supramolecular layers oriented parallel to the ac plane by C—H...O interactions. These layers then stack in an ABCD pattern along the b-axis direction by additional C—H...O interactions to give the full three-dimensional crystal structure. The central chain in the dipyridylamide molecule has an anti–gauche conformation.
topic	crystal structure isophthalic acid pyridin-4-ylmethanone propane-1,3-diyl supramolecular layers hydrogen bonding
url	http://scripts.iucr.org/cgi-bin/paper?S1600536814021679
work_keys_str_mv	AT nathanhmurray crystalstructureofpropane13diylbispiperidine41diylbispyridin4ylmethanoneisophthalicacid11 AT shannonmbiros crystalstructureofpropane13diylbispiperidine41diylbispyridin4ylmethanoneisophthalicacid11 AT robertlladuca crystalstructureofpropane13diylbispiperidine41diylbispyridin4ylmethanoneisophthalicacid11
_version_	1725232588833947648

Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–isophthalic acid (1/1)

Similar Items