Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution
The inhibition and the effect of temperature and concentration of trans-4-hydroxy-4′-stilbazole on the corrosion of mild steel in 1 M HCl solution was investigated by weight loss experiments at temperatures ranging from 303 to 343 K. The studied inhibitor concentrations were between 1×10−7 M and 1×1...
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2012-01-01
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Series: | International Journal of Corrosion |
Online Access: | http://dx.doi.org/10.1155/2012/380329 |
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doaj-c68c6df353a7445eaa03b544f5b022872020-11-24T23:02:04ZengHindawi LimitedInternational Journal of Corrosion1687-93251687-93332012-01-01201210.1155/2012/380329380329Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl SolutionAyssar Nahlé0Ideisan I. Abu-Abdoun1Ibrahim Abdel-Rahman2Department of Chemistry, College of Sciences, University of Sharjah, P.O. Box 27272, Sharjah, United Arab EmiratesDepartment of Chemistry, College of Sciences, University of Sharjah, P.O. Box 27272, Sharjah, United Arab EmiratesDepartment of Chemistry, College of Sciences, University of Sharjah, P.O. Box 27272, Sharjah, United Arab EmiratesThe inhibition and the effect of temperature and concentration of trans-4-hydroxy-4′-stilbazole on the corrosion of mild steel in 1 M HCl solution was investigated by weight loss experiments at temperatures ranging from 303 to 343 K. The studied inhibitor concentrations were between 1×10−7 M and 1×10−3 M. The percentage inhibition increased with the increase of the concentration of the inhibitor. The percentage inhibition reached about 94% at the concentration of 1×10−3 M and 303 K. On the other hand, the percentage inhibition decreased with the increase of temperature. Using the Temkin adsorption isotherm, the thermodynamic parameters for the adsorption of this inhibitor on the metal surface were calculated. Trans-4-hydroxy-4′-stilbazole was found to be a potential corrosion inhibitor since it contained not only nitrogen and oxygen, but also phenyl and pyridine rings that are joined together with a double bond (–C=C–) in conjugation with these rings.http://dx.doi.org/10.1155/2012/380329 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Ayssar Nahlé Ideisan I. Abu-Abdoun Ibrahim Abdel-Rahman |
spellingShingle |
Ayssar Nahlé Ideisan I. Abu-Abdoun Ibrahim Abdel-Rahman Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution International Journal of Corrosion |
author_facet |
Ayssar Nahlé Ideisan I. Abu-Abdoun Ibrahim Abdel-Rahman |
author_sort |
Ayssar Nahlé |
title |
Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution |
title_short |
Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution |
title_full |
Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution |
title_fullStr |
Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution |
title_full_unstemmed |
Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution |
title_sort |
effect of temperature on the corrosion inhibition of trans-4-hydroxy-4′-stilbazole on mild steel in hcl solution |
publisher |
Hindawi Limited |
series |
International Journal of Corrosion |
issn |
1687-9325 1687-9333 |
publishDate |
2012-01-01 |
description |
The inhibition and the effect of temperature and concentration of trans-4-hydroxy-4′-stilbazole on the corrosion of mild steel in 1 M HCl solution was investigated by weight loss experiments at temperatures ranging from 303 to 343 K. The studied inhibitor concentrations were between 1×10−7 M and 1×10−3 M. The percentage inhibition increased with the increase of the concentration of the inhibitor. The percentage inhibition reached about 94% at the concentration of 1×10−3 M and 303 K. On the other hand, the percentage inhibition decreased with the increase of temperature. Using the Temkin adsorption isotherm, the thermodynamic parameters for the adsorption of this inhibitor on the metal surface were calculated. Trans-4-hydroxy-4′-stilbazole was found to be a potential corrosion inhibitor since it contained not only nitrogen and oxygen, but also phenyl and pyridine rings that are joined together with a double bond (–C=C–) in conjugation with these rings. |
url |
http://dx.doi.org/10.1155/2012/380329 |
work_keys_str_mv |
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