Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution

The inhibition and the effect of temperature and concentration of trans-4-hydroxy-4′-stilbazole on the corrosion of mild steel in 1 M HCl solution was investigated by weight loss experiments at temperatures ranging from 303 to 343 K. The studied inhibitor concentrations were between 1×10−7 M and 1×1...

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Main Authors: Ayssar Nahlé, Ideisan I. Abu-Abdoun, Ibrahim Abdel-Rahman
Format: Article
Language:English
Published: Hindawi Limited 2012-01-01
Series:International Journal of Corrosion
Online Access:http://dx.doi.org/10.1155/2012/380329
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spelling doaj-c68c6df353a7445eaa03b544f5b022872020-11-24T23:02:04ZengHindawi LimitedInternational Journal of Corrosion1687-93251687-93332012-01-01201210.1155/2012/380329380329Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl SolutionAyssar Nahlé0Ideisan I. Abu-Abdoun1Ibrahim Abdel-Rahman2Department of Chemistry, College of Sciences, University of Sharjah, P.O. Box 27272, Sharjah, United Arab EmiratesDepartment of Chemistry, College of Sciences, University of Sharjah, P.O. Box 27272, Sharjah, United Arab EmiratesDepartment of Chemistry, College of Sciences, University of Sharjah, P.O. Box 27272, Sharjah, United Arab EmiratesThe inhibition and the effect of temperature and concentration of trans-4-hydroxy-4′-stilbazole on the corrosion of mild steel in 1 M HCl solution was investigated by weight loss experiments at temperatures ranging from 303 to 343 K. The studied inhibitor concentrations were between 1×10−7 M and 1×10−3 M. The percentage inhibition increased with the increase of the concentration of the inhibitor. The percentage inhibition reached about 94% at the concentration of 1×10−3 M and 303 K. On the other hand, the percentage inhibition decreased with the increase of temperature. Using the Temkin adsorption isotherm, the thermodynamic parameters for the adsorption of this inhibitor on the metal surface were calculated. Trans-4-hydroxy-4′-stilbazole was found to be a potential corrosion inhibitor since it contained not only nitrogen and oxygen, but also phenyl and pyridine rings that are joined together with a double bond (–C=C–) in conjugation with these rings.http://dx.doi.org/10.1155/2012/380329
collection DOAJ
language English
format Article
sources DOAJ
author Ayssar Nahlé
Ideisan I. Abu-Abdoun
Ibrahim Abdel-Rahman
spellingShingle Ayssar Nahlé
Ideisan I. Abu-Abdoun
Ibrahim Abdel-Rahman
Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution
International Journal of Corrosion
author_facet Ayssar Nahlé
Ideisan I. Abu-Abdoun
Ibrahim Abdel-Rahman
author_sort Ayssar Nahlé
title Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution
title_short Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution
title_full Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution
title_fullStr Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution
title_full_unstemmed Effect of Temperature on the Corrosion Inhibition of Trans-4-Hydroxy-4′-Stilbazole on Mild Steel in HCl Solution
title_sort effect of temperature on the corrosion inhibition of trans-4-hydroxy-4′-stilbazole on mild steel in hcl solution
publisher Hindawi Limited
series International Journal of Corrosion
issn 1687-9325
1687-9333
publishDate 2012-01-01
description The inhibition and the effect of temperature and concentration of trans-4-hydroxy-4′-stilbazole on the corrosion of mild steel in 1 M HCl solution was investigated by weight loss experiments at temperatures ranging from 303 to 343 K. The studied inhibitor concentrations were between 1×10−7 M and 1×10−3 M. The percentage inhibition increased with the increase of the concentration of the inhibitor. The percentage inhibition reached about 94% at the concentration of 1×10−3 M and 303 K. On the other hand, the percentage inhibition decreased with the increase of temperature. Using the Temkin adsorption isotherm, the thermodynamic parameters for the adsorption of this inhibitor on the metal surface were calculated. Trans-4-hydroxy-4′-stilbazole was found to be a potential corrosion inhibitor since it contained not only nitrogen and oxygen, but also phenyl and pyridine rings that are joined together with a double bond (–C=C–) in conjugation with these rings.
url http://dx.doi.org/10.1155/2012/380329
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