6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione)
Microwave irradiation of maleimide with an excess of furan in water exclusively yields the corresponding exo-cycloadduct in good yield (87%) in 1 hour at 90 oC. Alkylation of the imido nitrogen with tetraethylene glycol under Mitsunobu conditions gives the ROMP monomer in 81% yield.
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| Format: | Article |
| Language: | English |
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MDPI AG
2009-11-01
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| Series: | Molbank |
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| Online Access: | http://www.mdpi.com/1422-8599/2009/4/M638/ |
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doaj-c689e94a4367401f8d663cbfca957e55 |
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Article |
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doaj-c689e94a4367401f8d663cbfca957e552020-11-24T20:51:49ZengMDPI AGMolbank1422-85992009-11-0120094M63810.3390/M6386-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione)David M. GoodenMicrowave irradiation of maleimide with an excess of furan in water exclusively yields the corresponding exo-cycloadduct in good yield (87%) in 1 hour at 90 oC. Alkylation of the imido nitrogen with tetraethylene glycol under Mitsunobu conditions gives the ROMP monomer in 81% yield. http://www.mdpi.com/1422-8599/2009/4/M638/n/a |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
David M. Gooden |
| spellingShingle |
David M. Gooden 6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) Molbank n/a |
| author_facet |
David M. Gooden |
| author_sort |
David M. Gooden |
| title |
6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) |
| title_short |
6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) |
| title_full |
6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) |
| title_fullStr |
6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) |
| title_full_unstemmed |
6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) |
| title_sort |
6-(4-(2-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) |
| publisher |
MDPI AG |
| series |
Molbank |
| issn |
1422-8599 |
| publishDate |
2009-11-01 |
| description |
Microwave irradiation of maleimide with an excess of furan in water exclusively yields the corresponding exo-cycloadduct in good yield (87%) in 1 hour at 90 oC. Alkylation of the imido nitrogen with tetraethylene glycol under Mitsunobu conditions gives the ROMP monomer in 81% yield. |
| topic |
n/a |
| url |
http://www.mdpi.com/1422-8599/2009/4/M638/ |
| work_keys_str_mv |
AT davidmgooden 642222hydroxyethoxyethoxyethoxyethyl10oxa4azatricyclo521026dec8ene35dione |
| _version_ |
1716801052911599616 |