THE DETERMINATION OF OPTIMUM CONDITION FOR THE SYNTHESIS OF ALKYL MONOETHANOLAMIDE FROM PALM KERNEL OIL

THE DETERMINATION OF OPTIMUM CONDITION FOR THE SYNTHESIS OF ALKYL MONOETHANOLAMIDE FROM PALM KERNEL OIL

Synthesis of alkyl monoethanolamide from palm kernel oil was done by two steps reaction that are esterification and amidation. The esterification, that is the reaction between palm kernel oil and methanol with mole ratio of 1:3 using acid catalyst (H2SO4) 4 % at temperature 60 OC for two hours, resu...

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Main Authors: Hilyati Hilyati, Wuryaningsih Wuryaningsih, M. Nasir, Tasrif Tasrif, T. Beuna
Format: Article
Language:English
Published: Universitas Gadjah Mada 2010-06-01
Series:Indonesian Journal of Chemistry
Online Access:https://jurnal.ugm.ac.id/ijc/article/view/21859
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spelling doaj-c6711b6529f146819e363b3526ba22a62020-11-24T22:24:07ZengUniversitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782010-06-0142889310.22146/ijc.2185914957THE DETERMINATION OF OPTIMUM CONDITION FOR THE SYNTHESIS OF ALKYL MONOETHANOLAMIDE FROM PALM KERNEL OILHilyati Hilyati0Wuryaningsih Wuryaningsih1M. Nasir2Tasrif Tasrif3T. Beuna4Pusat Penelitian Kimia –LIPI, Kawasan PUSPIPTEK-SerpongPusat Penelitian Kimia –LIPI, Kawasan PUSPIPTEK-SerpongPusat Penelitian Kimia –LIPI, Kawasan PUSPIPTEK-SerpongPusat Penelitian Kimia –LIPI, Kawasan PUSPIPTEK-SerpongPusat Penelitian Kimia –LIPI, Kawasan PUSPIPTEK-SerpongSynthesis of alkyl monoethanolamide from palm kernel oil was done by two steps reaction that are esterification and amidation. The esterification, that is the reaction between palm kernel oil and methanol with mole ratio of 1:3 using acid catalyst (H2SO4) 4 % at temperature 60 OC for two hours, results in methyl ester palm kernel oil. The methyl ester product was produced by amidation reaction on any variation of time, temperature, catalyst, catalyst concentration and ratio of the reactan. The best result of the synthesis (amide conversion of 98.15 %) was obtained at temperature of 160 OC for 6 hours with mole ratio of methyl ester palm kernel oil to ethanol amine (ratio of the reactan) 1:1 using KOH catalyst 0.5 % and H2SO4 catalyst 0.5 %.   Keywords: alkyl mono ethanol amide, surfactant, palm kernel oil, esterification, methyl ester, emulsifierhttps://jurnal.ugm.ac.id/ijc/article/view/21859
collection DOAJ
language English
format Article
sources DOAJ
author Hilyati Hilyati
Wuryaningsih Wuryaningsih
M. Nasir
Tasrif Tasrif
T. Beuna
spellingShingle Hilyati Hilyati
Wuryaningsih Wuryaningsih
M. Nasir
Tasrif Tasrif
T. Beuna
THE DETERMINATION OF OPTIMUM CONDITION FOR THE SYNTHESIS OF ALKYL MONOETHANOLAMIDE FROM PALM KERNEL OIL
Indonesian Journal of Chemistry
author_facet Hilyati Hilyati
Wuryaningsih Wuryaningsih
M. Nasir
Tasrif Tasrif
T. Beuna
author_sort Hilyati Hilyati
title THE DETERMINATION OF OPTIMUM CONDITION FOR THE SYNTHESIS OF ALKYL MONOETHANOLAMIDE FROM PALM KERNEL OIL
title_short THE DETERMINATION OF OPTIMUM CONDITION FOR THE SYNTHESIS OF ALKYL MONOETHANOLAMIDE FROM PALM KERNEL OIL
title_full THE DETERMINATION OF OPTIMUM CONDITION FOR THE SYNTHESIS OF ALKYL MONOETHANOLAMIDE FROM PALM KERNEL OIL
title_fullStr THE DETERMINATION OF OPTIMUM CONDITION FOR THE SYNTHESIS OF ALKYL MONOETHANOLAMIDE FROM PALM KERNEL OIL
title_full_unstemmed THE DETERMINATION OF OPTIMUM CONDITION FOR THE SYNTHESIS OF ALKYL MONOETHANOLAMIDE FROM PALM KERNEL OIL
title_sort determination of optimum condition for the synthesis of alkyl monoethanolamide from palm kernel oil
publisher Universitas Gadjah Mada
series Indonesian Journal of Chemistry
issn 1411-9420
2460-1578
publishDate 2010-06-01
description Synthesis of alkyl monoethanolamide from palm kernel oil was done by two steps reaction that are esterification and amidation. The esterification, that is the reaction between palm kernel oil and methanol with mole ratio of 1:3 using acid catalyst (H2SO4) 4 % at temperature 60 OC for two hours, results in methyl ester palm kernel oil. The methyl ester product was produced by amidation reaction on any variation of time, temperature, catalyst, catalyst concentration and ratio of the reactan. The best result of the synthesis (amide conversion of 98.15 %) was obtained at temperature of 160 OC for 6 hours with mole ratio of methyl ester palm kernel oil to ethanol amine (ratio of the reactan) 1:1 using KOH catalyst 0.5 % and H2SO4 catalyst 0.5 %.   Keywords: alkyl mono ethanol amide, surfactant, palm kernel oil, esterification, methyl ester, emulsifier
url https://jurnal.ugm.ac.id/ijc/article/view/21859
work_keys_str_mv AT hilyatihilyati thedeterminationofoptimumconditionforthesynthesisofalkylmonoethanolamidefrompalmkerneloil
AT wuryaningsihwuryaningsih thedeterminationofoptimumconditionforthesynthesisofalkylmonoethanolamidefrompalmkerneloil
AT mnasir thedeterminationofoptimumconditionforthesynthesisofalkylmonoethanolamidefrompalmkerneloil
AT tasriftasrif thedeterminationofoptimumconditionforthesynthesisofalkylmonoethanolamidefrompalmkerneloil
AT tbeuna thedeterminationofoptimumconditionforthesynthesisofalkylmonoethanolamidefrompalmkerneloil
AT hilyatihilyati determinationofoptimumconditionforthesynthesisofalkylmonoethanolamidefrompalmkerneloil
AT wuryaningsihwuryaningsih determinationofoptimumconditionforthesynthesisofalkylmonoethanolamidefrompalmkerneloil
AT mnasir determinationofoptimumconditionforthesynthesisofalkylmonoethanolamidefrompalmkerneloil
AT tasriftasrif determinationofoptimumconditionforthesynthesisofalkylmonoethanolamidefrompalmkerneloil
AT tbeuna determinationofoptimumconditionforthesynthesisofalkylmonoethanolamidefrompalmkerneloil
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