Synthesis of Ethano-Bridged Diazapolycenes as Potential Precursors for Diazapolycenes and Their Properties

A series of ethanodiazapolycenes were prepared in 87%–89% yields by Friedländer reactions of three o-aminoarenecarbaldehydes with bicyclo[2.2.2]octane-2,5-dione and their spectral, thermal, and structural properties were studied. Subsequent attempts to convert them to diazapolycenes have proved unsu...

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Bibliographic Details
Main Authors: Moinul Karim, Yurngdong Jahng
Format: Article
Language:English
Published: MDPI AG 2016-03-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/21/4/407
Description
Summary:A series of ethanodiazapolycenes were prepared in 87%–89% yields by Friedländer reactions of three o-aminoarenecarbaldehydes with bicyclo[2.2.2]octane-2,5-dione and their spectral, thermal, and structural properties were studied. Subsequent attempts to convert them to diazapolycenes have proved unsuccessful.
ISSN:1420-3049