Bis(2,4,6-trimethylphenyl)zinc(II)

The title compound, [Zn(C9H11)2] or Mes2Zn (Mes = mesityl = 2,4,6-trimethylphenyl), crystallizes with a quarter of a molecule in the asymmetric unit. The ZnII atom is in a strictly linear environment with a Zn—C bond length of 1.951 (5) Å. Due t...

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Bibliographic Details
Main Authors: Sven Krieck, Helmar Görls, Matthias Westerhausen
Format: Article
Language:English
Published: International Union of Crystallography 2009-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809023186
Description
Summary:The title compound, [Zn(C9H11)2] or Mes2Zn (Mes = mesityl = 2,4,6-trimethylphenyl), crystallizes with a quarter of a molecule in the asymmetric unit. The ZnII atom is in a strictly linear environment with a Zn—C bond length of 1.951 (5) Å. Due to the imposed 2/m symmetry, both aromatic rings are coplanar. One of the methyl groups is disordered over two equally occupied positions.
ISSN:1600-5368