Crystal structure of catena-poly[[[tetraaquazinc(II)]-μ-1,4-bis[4-(1H-imidazol-1-yl)benzoyl]piperazine] dinitrate monohydrate]

Crystal structure of catena-poly[[[tetraaquazinc(II)]-μ-1,4-bis[4-(1H-imidazol-1-yl)benzoyl]piperazine] dinitrate monohydrate]

In the title polymeric complex, {[Zn(C24H22N6O2)(H2O)4](NO3)2·2H2O}n, the ZnII cation, located about a twofold rotation axis, is coordinated by two imidazole groups and four water molecules in a distorted N2O4 octahedral geometry; among the four coordinate water molecules, two are located on the sam...

Full description

Bibliographic Details
Main Authors: Chen Hou, Hong-Mei Gan, Jia-Cheng Liu
Format: Article
Language:English
Published: International Union of Crystallography 2015-05-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
zinc complex
one-dimensional coordination polymer
piperazine
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015007719
id doaj-c5e1dafdf0e94c0fa98ddfbf9bb27d59
record_format Article
spelling doaj-c5e1dafdf0e94c0fa98ddfbf9bb27d592020-11-25T00:13:30ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-05-01715m120m12110.1107/S2056989015007719xu5847Crystal structure of catena-poly[[[tetraaquazinc(II)]-μ-1,4-bis[4-(1H-imidazol-1-yl)benzoyl]piperazine] dinitrate monohydrate]Chen Hou0Hong-Mei Gan1Jia-Cheng Liu2College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of ChinaCollege of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of ChinaCollege of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of ChinaIn the title polymeric complex, {[Zn(C24H22N6O2)(H2O)4](NO3)2·2H2O}n, the ZnII cation, located about a twofold rotation axis, is coordinated by two imidazole groups and four water molecules in a distorted N2O4 octahedral geometry; among the four coordinate water molecules, two are located on the same twofold rotation axis. The 1,4-bis[4-(1H-imidazol-1-yl)benzoyl]piperazine] ligand is centro-symmetric, with the centroid of the piperazine ring located on an inversion center, and bridges the ZnII cations, forming polymeric chains propagating along [201]. In the crystal, O—H...O and weak C—H...O hydrogen bonds link the polymeric chains, nitrate anions and solvent water molecules into a three-dimensional supramolecular architecture. A short O...O contact of 2.823 (13) Å is observed between neighboring nitrate anions.http://scripts.iucr.org/cgi-bin/paper?S2056989015007719crystal structurezinc complexone-dimensional coordination polymerpiperazine
collection DOAJ
language English
format Article
sources DOAJ
author Chen Hou
Hong-Mei Gan
Jia-Cheng Liu
spellingShingle Chen Hou
Hong-Mei Gan
Jia-Cheng Liu
Crystal structure of catena-poly[[[tetraaquazinc(II)]-μ-1,4-bis[4-(1H-imidazol-1-yl)benzoyl]piperazine] dinitrate monohydrate]
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
zinc complex
one-dimensional coordination polymer
piperazine
author_facet Chen Hou
Hong-Mei Gan
Jia-Cheng Liu
author_sort Chen Hou
title Crystal structure of catena-poly[[[tetraaquazinc(II)]-μ-1,4-bis[4-(1H-imidazol-1-yl)benzoyl]piperazine] dinitrate monohydrate]
title_short Crystal structure of catena-poly[[[tetraaquazinc(II)]-μ-1,4-bis[4-(1H-imidazol-1-yl)benzoyl]piperazine] dinitrate monohydrate]
title_full Crystal structure of catena-poly[[[tetraaquazinc(II)]-μ-1,4-bis[4-(1H-imidazol-1-yl)benzoyl]piperazine] dinitrate monohydrate]
title_fullStr Crystal structure of catena-poly[[[tetraaquazinc(II)]-μ-1,4-bis[4-(1H-imidazol-1-yl)benzoyl]piperazine] dinitrate monohydrate]
title_full_unstemmed Crystal structure of catena-poly[[[tetraaquazinc(II)]-μ-1,4-bis[4-(1H-imidazol-1-yl)benzoyl]piperazine] dinitrate monohydrate]
title_sort crystal structure of catena-poly[[[tetraaquazinc(ii)]-μ-1,4-bis[4-(1h-imidazol-1-yl)benzoyl]piperazine] dinitrate monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2015-05-01
description In the title polymeric complex, {[Zn(C24H22N6O2)(H2O)4](NO3)2·2H2O}n, the ZnII cation, located about a twofold rotation axis, is coordinated by two imidazole groups and four water molecules in a distorted N2O4 octahedral geometry; among the four coordinate water molecules, two are located on the same twofold rotation axis. The 1,4-bis[4-(1H-imidazol-1-yl)benzoyl]piperazine] ligand is centro-symmetric, with the centroid of the piperazine ring located on an inversion center, and bridges the ZnII cations, forming polymeric chains propagating along [201]. In the crystal, O—H...O and weak C—H...O hydrogen bonds link the polymeric chains, nitrate anions and solvent water molecules into a three-dimensional supramolecular architecture. A short O...O contact of 2.823 (13) Å is observed between neighboring nitrate anions.
topic crystal structure
zinc complex
one-dimensional coordination polymer
piperazine
url http://scripts.iucr.org/cgi-bin/paper?S2056989015007719
work_keys_str_mv AT chenhou crystalstructureofcatenapolytetraaquazinciim14bis41himidazol1ylbenzoylpiperazinedinitratemonohydrate
AT hongmeigan crystalstructureofcatenapolytetraaquazinciim14bis41himidazol1ylbenzoylpiperazinedinitratemonohydrate
AT jiachengliu crystalstructureofcatenapolytetraaquazinciim14bis41himidazol1ylbenzoylpiperazinedinitratemonohydrate
_version_ 1725393927577534464

Similar Items