The role of the 5f valence orbitals of early actinides in chemical bonding

Understanding the chemistry of heavy radioactive elements is crucial to harnessing them for fuel and medicine. Here, the authors combine advanced X-ray spectroscopy and modelling to the study the chemical bonding of the 5fvalence orbitals of uranium, neptunium and plutonium.

Bibliographic Details
Main Authors:	T. Vitova, I. Pidchenko, D. Fellhauer, P. S. Bagus, Y. Joly, T. Pruessmann, S. Bahl, E. Gonzalez-Robles, J. Rothe, M. Altmaier, M. A. Denecke, H. Geckeis
Format:	Article
Language:	English
Published:	Nature Publishing Group 2017-07-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/ncomms16053

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spelling	doaj-c5c2920a9dd24959b0c2bc1df62f72f92021-05-11T07:34:25ZengNature Publishing GroupNature Communications2041-17232017-07-01811910.1038/ncomms16053The role of the 5f valence orbitals of early actinides in chemical bondingT. Vitova0I. Pidchenko1D. Fellhauer2P. S. Bagus3Y. Joly4T. Pruessmann5S. Bahl6E. Gonzalez-Robles7J. Rothe8M. Altmaier9M. A. Denecke10H. Geckeis11Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE)Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE)Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE)Department of Chemistry, University of North TexasUniversity Grenoble Alpes, Inst NEELKarlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE)Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE)Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE)Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE)Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE)Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE)Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE)Understanding the chemistry of heavy radioactive elements is crucial to harnessing them for fuel and medicine. Here, the authors combine advanced X-ray spectroscopy and modelling to the study the chemical bonding of the 5fvalence orbitals of uranium, neptunium and plutonium.https://doi.org/10.1038/ncomms16053
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	T. Vitova I. Pidchenko D. Fellhauer P. S. Bagus Y. Joly T. Pruessmann S. Bahl E. Gonzalez-Robles J. Rothe M. Altmaier M. A. Denecke H. Geckeis
spellingShingle	T. Vitova I. Pidchenko D. Fellhauer P. S. Bagus Y. Joly T. Pruessmann S. Bahl E. Gonzalez-Robles J. Rothe M. Altmaier M. A. Denecke H. Geckeis The role of the 5f valence orbitals of early actinides in chemical bonding Nature Communications
author_facet	T. Vitova I. Pidchenko D. Fellhauer P. S. Bagus Y. Joly T. Pruessmann S. Bahl E. Gonzalez-Robles J. Rothe M. Altmaier M. A. Denecke H. Geckeis
author_sort	T. Vitova
title	The role of the 5f valence orbitals of early actinides in chemical bonding
title_short	The role of the 5f valence orbitals of early actinides in chemical bonding
title_full	The role of the 5f valence orbitals of early actinides in chemical bonding
title_fullStr	The role of the 5f valence orbitals of early actinides in chemical bonding
title_full_unstemmed	The role of the 5f valence orbitals of early actinides in chemical bonding
title_sort	role of the 5f valence orbitals of early actinides in chemical bonding
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2017-07-01
description	Understanding the chemistry of heavy radioactive elements is crucial to harnessing them for fuel and medicine. Here, the authors combine advanced X-ray spectroscopy and modelling to the study the chemical bonding of the 5fvalence orbitals of uranium, neptunium and plutonium.
url	https://doi.org/10.1038/ncomms16053
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The role of the 5f valence orbitals of early actinides in chemical bonding

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