Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black

A model of rubber with a cross-linked rubber layer on a carbon black filler has been proposed. The cross-links are the result of free radical reactions generated by carbon atoms with unpaired electrons at the edge of graphitic sheets in a carbon black filler. The experimental study of the cross-link...

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Main Authors:	Alexey V. Kondyurin, Anastasia Yu. Eliseeva, Alexander L. Svistkov
Format:	Article
Language:	English
Published:	MDPI AG 2018-10-01
Series:	Materials
Subjects:	rubber carbon black glassy layer graphite free radicals crosslinking ellipsometry FTIR
Online Access:	http://www.mdpi.com/1996-1944/11/10/1992

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spelling	doaj-c576f1b4aa534c95ba757dc29ac581632020-11-24T22:23:08ZengMDPI AGMaterials1996-19442018-10-011110199210.3390/ma11101992ma11101992Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon BlackAlexey V. Kondyurin0Anastasia Yu. Eliseeva1Alexander L. Svistkov2School of Physics, University of Sydney, 2006 Sydney, AustraliaICMM UrB RAS, Academika Koroleva st, 1, 614013 Perm, RussiaICMM UrB RAS, Academika Koroleva st, 1, 614013 Perm, RussiaA model of rubber with a cross-linked rubber layer on a carbon black filler has been proposed. The cross-links are the result of free radical reactions generated by carbon atoms with unpaired electrons at the edge of graphitic sheets in a carbon black filler. The experimental study of the cross-linking reactions in polyisoprene was done on a flat carbonized surface after ion beam implantation. The cross-linking process in the polyisoprene macromolecules between two particles was simulated. The model with a cross-linked rubber layer on a carbon filler as a “glassy layer” explains the mechanical properties of the rubber materials.http://www.mdpi.com/1996-1944/11/10/1992rubbercarbon blackglassy layergraphitefree radicalscrosslinkingellipsometryFTIR
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Alexey V. Kondyurin Anastasia Yu. Eliseeva Alexander L. Svistkov
spellingShingle	Alexey V. Kondyurin Anastasia Yu. Eliseeva Alexander L. Svistkov Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black Materials rubber carbon black glassy layer graphite free radicals crosslinking ellipsometry FTIR
author_facet	Alexey V. Kondyurin Anastasia Yu. Eliseeva Alexander L. Svistkov
author_sort	Alexey V. Kondyurin
title	Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black
title_short	Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black
title_full	Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black
title_fullStr	Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black
title_full_unstemmed	Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black
title_sort	bound (“glassy”) rubber as a free radical cross-linked rubber layer on a carbon black
publisher	MDPI AG
series	Materials
issn	1996-1944
publishDate	2018-10-01
description	A model of rubber with a cross-linked rubber layer on a carbon black filler has been proposed. The cross-links are the result of free radical reactions generated by carbon atoms with unpaired electrons at the edge of graphitic sheets in a carbon black filler. The experimental study of the cross-linking reactions in polyisoprene was done on a flat carbonized surface after ion beam implantation. The cross-linking process in the polyisoprene macromolecules between two particles was simulated. The model with a cross-linked rubber layer on a carbon filler as a “glassy layer” explains the mechanical properties of the rubber materials.
topic	rubber carbon black glassy layer graphite free radicals crosslinking ellipsometry FTIR
url	http://www.mdpi.com/1996-1944/11/10/1992
work_keys_str_mv	AT alexeyvkondyurin boundglassyrubberasafreeradicalcrosslinkedrubberlayeronacarbonblack AT anastasiayueliseeva boundglassyrubberasafreeradicalcrosslinkedrubberlayeronacarbonblack AT alexanderlsvistkov boundglassyrubberasafreeradicalcrosslinkedrubberlayeronacarbonblack
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Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black

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