Bis{4-bromo-2-[(naphthalen-1-ylimino)methyl]phenolato-κ2N,O}copper(II)

Bis{4-bromo-2-[(naphthalen-1-ylimino)methyl]phenolato-κ2N,O}copper(II)

The title complex, [Cu(C17H11BrNO)2], lies on a centre of inversion. The chelating Schiff base anions define a square-planar N2O2 donor set. The nearly perpendicular orientation of the naphthyl residues of the chelate ring [dihedral angle = 82.12 (12)°] precludes the CuII...

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Main Authors: Babak Mirtamizdoust, Edward R. T. Tiekink, Gholam Hossein Shahverdizadeh, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2012-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812004989
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spelling doaj-c5758ca91fc542e29ba157fe0a3a8b912020-11-25T01:17:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m278m27810.1107/S1600536812004989Bis{4-bromo-2-[(naphthalen-1-ylimino)methyl]phenolato-κ2N,O}copper(II)Babak MirtamizdoustEdward R. T. TiekinkGholam Hossein ShahverdizadehSeik Weng NgThe title complex, [Cu(C17H11BrNO)2], lies on a centre of inversion. The chelating Schiff base anions define a square-planar N2O2 donor set. The nearly perpendicular orientation of the naphthyl residues of the chelate ring [dihedral angle = 82.12 (12)°] precludes the CuII centre from additional coordination. In the refinement, the naphthyl rings were found to be disordered over two positions.; the major component has a site occupancy of 0.667 (4).http://scripts.iucr.org/cgi-bin/paper?S1600536812004989
collection DOAJ
language English
format Article
sources DOAJ
author Babak Mirtamizdoust
Edward R. T. Tiekink
Gholam Hossein Shahverdizadeh
Seik Weng Ng
spellingShingle Babak Mirtamizdoust
Edward R. T. Tiekink
Gholam Hossein Shahverdizadeh
Seik Weng Ng
Bis{4-bromo-2-[(naphthalen-1-ylimino)methyl]phenolato-κ2N,O}copper(II)
Acta Crystallographica Section E
author_facet Babak Mirtamizdoust
Edward R. T. Tiekink
Gholam Hossein Shahverdizadeh
Seik Weng Ng
author_sort Babak Mirtamizdoust
title Bis{4-bromo-2-[(naphthalen-1-ylimino)methyl]phenolato-κ2N,O}copper(II)
title_short Bis{4-bromo-2-[(naphthalen-1-ylimino)methyl]phenolato-κ2N,O}copper(II)
title_full Bis{4-bromo-2-[(naphthalen-1-ylimino)methyl]phenolato-κ2N,O}copper(II)
title_fullStr Bis{4-bromo-2-[(naphthalen-1-ylimino)methyl]phenolato-κ2N,O}copper(II)
title_full_unstemmed Bis{4-bromo-2-[(naphthalen-1-ylimino)methyl]phenolato-κ2N,O}copper(II)
title_sort bis{4-bromo-2-[(naphthalen-1-ylimino)methyl]phenolato-κ2n,o}copper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-03-01
description The title complex, [Cu(C17H11BrNO)2], lies on a centre of inversion. The chelating Schiff base anions define a square-planar N2O2 donor set. The nearly perpendicular orientation of the naphthyl residues of the chelate ring [dihedral angle = 82.12 (12)°] precludes the CuII centre from additional coordination. In the refinement, the naphthyl rings were found to be disordered over two positions.; the major component has a site occupancy of 0.667 (4).
url http://scripts.iucr.org/cgi-bin/paper?S1600536812004989
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AT edwardrttiekink bis4bromo2naphthalen1yliminomethylphenolatoamp9542nocopperii
AT gholamhosseinshahverdizadeh bis4bromo2naphthalen1yliminomethylphenolatoamp9542nocopperii
AT seikwengng bis4bromo2naphthalen1yliminomethylphenolatoamp9542nocopperii
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