Two-dimensional x-ray correlation spectroscopy of remote core states

Two-dimensional x-ray correlation spectroscopy of remote core states

Nonlinear all-X-ray signals that involve large core-atom separation compared to the X-ray wavelengths may not be described by the dipole approximation since they contain additional phase factors. Expressions for the rotationally averaged 2D X-ray photon echo signals from randomly oriented systems th...

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Bibliographic Details
Main Authors: Daniel Healion, Yu Zhang, Jason D. Biggs, Weijie Hua, Shaul Mukamel
Format: Article
Language:English
Published: AIP Publishing LLC and ACA 2014-01-01
Series:Structural Dynamics
Online Access:http://dx.doi.org/10.1063/1.4833560
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spelling doaj-c5598bb26a4c4cd3866d84814e50d8102020-11-24T21:04:44ZengAIP Publishing LLC and ACAStructural Dynamics2329-77782014-01-0111014101014101-1910.1063/1.4833560002401SDYTwo-dimensional x-ray correlation spectroscopy of remote core statesDaniel Healion0Yu Zhang1Jason D. Biggs2Weijie Hua3Shaul Mukamel4Department of Chemistry, University of California, 450 Rowland Hall, Irvine, California 92697-2025, USADepartment of Chemistry, University of California, 450 Rowland Hall, Irvine, California 92697-2025, USADepartment of Chemistry, University of California, 450 Rowland Hall, Irvine, California 92697-2025, USADepartment of Chemistry, University of California, 450 Rowland Hall, Irvine, California 92697-2025, USADepartment of Chemistry, University of California, 450 Rowland Hall, Irvine, California 92697-2025, USANonlinear all-X-ray signals that involve large core-atom separation compared to the X-ray wavelengths may not be described by the dipole approximation since they contain additional phase factors. Expressions for the rotationally averaged 2D X-ray photon echo signals from randomly oriented systems that take this position-dependent phase into account for arbitrary ratio between the core separation and the resonant wavelength are presented. Application is made to the Se K-edge of a selenium dipeptide system.http://dx.doi.org/10.1063/1.4833560
collection DOAJ
language English
format Article
sources DOAJ
author Daniel Healion
Yu Zhang
Jason D. Biggs
Weijie Hua
Shaul Mukamel
spellingShingle Daniel Healion
Yu Zhang
Jason D. Biggs
Weijie Hua
Shaul Mukamel
Two-dimensional x-ray correlation spectroscopy of remote core states
Structural Dynamics
author_facet Daniel Healion
Yu Zhang
Jason D. Biggs
Weijie Hua
Shaul Mukamel
author_sort Daniel Healion
title Two-dimensional x-ray correlation spectroscopy of remote core states
title_short Two-dimensional x-ray correlation spectroscopy of remote core states
title_full Two-dimensional x-ray correlation spectroscopy of remote core states
title_fullStr Two-dimensional x-ray correlation spectroscopy of remote core states
title_full_unstemmed Two-dimensional x-ray correlation spectroscopy of remote core states
title_sort two-dimensional x-ray correlation spectroscopy of remote core states
publisher AIP Publishing LLC and ACA
series Structural Dynamics
issn 2329-7778
publishDate 2014-01-01
description Nonlinear all-X-ray signals that involve large core-atom separation compared to the X-ray wavelengths may not be described by the dipole approximation since they contain additional phase factors. Expressions for the rotationally averaged 2D X-ray photon echo signals from randomly oriented systems that take this position-dependent phase into account for arbitrary ratio between the core separation and the resonant wavelength are presented. Application is made to the Se K-edge of a selenium dipeptide system.
url http://dx.doi.org/10.1063/1.4833560
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AT yuzhang twodimensionalxraycorrelationspectroscopyofremotecorestates
AT jasondbiggs twodimensionalxraycorrelationspectroscopyofremotecorestates
AT weijiehua twodimensionalxraycorrelationspectroscopyofremotecorestates
AT shaulmukamel twodimensionalxraycorrelationspectroscopyofremotecorestates
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